Perovskite solar cells (PSCs) have received a large amount of research funds due to their potential as a frontrunner in a new generation of solar cells; consequently, the desire to commercialize this technology is mounting. In this roadmap, the knowledge and the technological gaps between laboratory and industry are critically analyzed from the perspective of 5S criteria (Stability, Safety, Sustainability, Scalability, and Storage). To avoid any favoritism in the arguments toward commercializing this technology, herein, the average parameters of PSCs (photoconversion efficiency, durability, cost, manufacturability, and sustainability) estimated from previous studies are analyzed and discussed. Unique opportunities for PSCs in their current stage of achievements are identified, where application‐driven, instead of performance‐driven, developments are shown to favor their commercialization. Efforts required to improve the average performance of PSCs to state‐of‐the‐art levels are also identified and discussed.

Perovskite solar cells (PSCs) have received large amount of research funds due to their potential as a front runner in a new generation of solar cells; consequently, desire towards commercializing this technology is mounting. In this roadmap, the knowledge and the technological gaps between laboratory and industry are critically analyzed from the perspective of a 5S criterion (Stability, Safety, Sustainability, Scalability, and Storage). To avoid any favoritism in the arguments toward commercializing this technology, herein, the average parameters of PSCs (photoconversion efficiency, durability, cost, manufacturability, and sustainability) estimated from previous studies are analyzed and discussed. We identify unique opportunities for PSCs in their current stage of achievements, where application-driven, instead of performance-driven developments are shown to favor their commercialization. Efforts required for improving the average performance indicators of PSCs to the level of the state-ofthe art in photovoltaics are also identified and discussed.