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We present N2O emission data from 11 sites in the Neuse River watershed. Emissions were measured using a static surface enclosure technique deployed on eight sites on the main river channel and three tributary sites. Ancillary data collected included dissolved oxygen, nitrate, total nitrogen, ammonium, dissolved organic carbon, total phosphorus, and temperature. Analysis using standard linear models, and classification and regression trees (CART), indicated nitrate to be the primary driving variable associated with N2O emission, although dissolved organic carbon concentration and water temperature were positively related with N2O emission as well. Relationships between nitrate concentration and N2O emission were consistent with those found in previous studies, although the data presented here represent the lower end of the range for both variables among published studies. Using our measured N2O emission rates along with literature values for the ratio of nitrogen gas to N2O produced during denitrification, we estimate N loss via denitrification in the Neuse River is approximately 17% of the annual N load delivered to the estuary.

Caffeine has been suggested as a chemical indicator for domestic wastewater in freshwater systems, although it is not included in water quality monitoring programs. The Third Fork Creek watershed in Durham, NC, is highly urbanized, with a history of receiving untreated wastewater from leaking and overflowing sanitary sewers. The poor water quality originating in the Third Fork Creek watershed threatens its intended uses and jeopardizes drinking water, aquatic life, and recreational activities provided by Jordan Lake. Organic waste contaminants have been detected in both Third Fork Creek watershed and Jordan Lake; however, the sampling periods were temporary, resulting in a few samples collected during nonstorm periods. It is recommended that (1) the concentration of caffeine and other organic waste contaminants are determined during storm and nonstorm periods and (2) caffeine is monitored regularly with traditional water quality indicators to evaluate the health of Third Fork Creek watershed.