This work uses an ionic liquid (IL), 1-butyl-3-methylimidazolium acetate, as a solvent to study the sol/gel transition (SGT) and liquid crystal transition (LCT) of hydroxypropylcellulose (HPC) solution. The LCT concentration of HPC at room temperature is 7 wt%, which is slightly higher than its SGT concentration of 6 wt%. For HPC concentrations of over 7 wt%, three rheological approaches were utilized, and the parameters relaxation time, hysteresis ratio and loss modulus (G 00 ) are measured to determine the LCT temperature. The relaxation study concludes that the LC-critical concentration of HPC is 7 wt%. When HPC exceeds 7 wt%, the LC transition temperatures, ranging from 45 to 51°C, can be measured and are proportional to the HPC concentration. The rheological results are then confirmed by making observations under a polarized optical microscope. All results are highly mutually consistent. Most significantly, the rheological parameters adopted herein can be used as good indicators of the LC transition. Of those indicators, G 00 changes distinctly at the LCT point, and can thus be suggested to be the most helpful indicator in determining the LCT temperature.
We demonstrate the feasibility of using direct contact-printing in the fabrication of monochromatic and polychromatic organic light-emitting diodes (OLEDs). Bright devices with red, green, blue, and white contact-printed light-emitting layers with a respective maximum luminance of 29 000, 29 000, 4000, and 18 000 cd/m2 were obtained with sound film integrity by blending a polymeric host into a molecular host. For the red OLED as example, the maximum luminance was decreased from 29 000 to 5000 cd/m2 as only the polymeric host was used, or decreased to 7000 cd/m2 as only the molecular host was used. The markedly improved device performance achieved in the devices with blended hosts may be attributed to the employed polymeric host that contributed a good film-forming character, and the molecular host that contributed a good electroluminescence character.
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