Realization of advanced bio-interactive electronic devices requires mechanically compliant sensors with the ability to detect extremely large strain. Here, we design a new multifunctional carbon nanotube (CNT) based capacitive strain sensors which can detect strains up to 300% with excellent durability even after thousands of cycles. The CNT-based strain gauge devices exhibit deterministic and linear capacitive response throughout the whole strain range with a gauge factor very close to the predicted value (strictly 1), representing the highest sensitivity value. The strain tests reveal the presented strain gauge with excellent dynamic sensing ability without overshoot or relaxation, and ultrafast response at sub-second scale. Coupling these superior sensing capabilities to the high transparency, physical robustness and flexibility, we believe the designed stretchable multifunctional CNT-based strain gauge may have various potential applications in human friendly and wearable smart electronics, subsequently demonstrated by our prototypical data glove and respiration monitor.R ecent developments in flexible and stretchable electronics, either through structural consideration or by exploring novel materials 1,2 , have imparted otherwise rigid and brittle electronic devices mechanical compliance and bio-compatibility, paving the way for energy-efficient, lightweight, portable, wearable and even implantable electronics 3 . Examples include stretchable and large area display that can undergo complex deformations 4 , bio-inspired material and structural designs that enable bionic functions 5 , and printable sensory system capable of detecting planar strains, normal pressure, temperature, light, moisture and chemical/biological species 6 . Multifunctional sensors, in particular, with sensing abilities akin to or beyond those of human skin 6-12 , are essential for applications such as interactive electronics 13 , structural health monitoring 14 , smart clothing 15 , robotic systems with advanced sensing capabilities 16 , human motion detection 8 and so on. Among the various types of sensors, strain gauge is one of the most important smart sensors, which have been widely used in the measurements of strain, acceleration and tension, as well as structural health monitoring. Conventional strain gauges, made of metal foils, register resistance changes under tensile strains. Actually, mechanical compliance and large strain range (?5%), obviously not the case of metal foils, are required to meet the demands of wearable electronics 15 , human motion detection 8 and interactive robots 17 . Although mercury-in-rubber strain gauge has been used in the biological measurements for decades 18 , the maximum strain limit and toxicity of mercury still block their practically wide applications. In addition, the combination of conformability and optical transparency will facilitate intelligent electronics and self-powered robot where strain sensors are integrated with optoelectronic devices and direct observation through the devices is ne...
One of the most critical aspects in the preparation of single-walled carbon nanotubes (SWCNTs)/ conducting polymer hybrid electrodes is to improve the energy density without seriously deteriorating their high power capability. Here, we report a ''skeleton/skin'' strategy for the preparation of freestanding, thin and flexible SWCNT/polyaniline (PANI) hybrid films by a simple in situ electrochemical polymerization method using directly grown SWCNT films with a continuous reticulate structure as template. In situ electrochemical polymerization can achieve effective deposition of PANI onto the surface of SWCNT bundles in the films and control the morphology and microstructure of the SWCNT/PANI hybrid films. In a SWCNT/PANI hybrid film, the directly grown SWCNT film with continuous reticulate architecture acts as the skeleton and PANI layers act as the skin. This unique continuous ''skeleton/skin'' structure ensures that these hybrid films have much higher conductivity compared to SWCNT/PANI composite films based on post-deposition SWCNT films. Flexible supercapacitors have been fabricated using the SWCNT/PANI hybrid films as both electrodes and charge collectors without metallic current collectors. High energy and power densities (131 W h kg À1 and 62.5 kW kg À1 , respectively) have been achieved for the optimized assembly. The high electrical conductivity and flexibility, in combination with continuous porous architecture, suggests that the asprepared ultrathin free-standing SWCNT/PANI hybrid films have significant potential as promising electrode materials for thin, lightweight and flexible energy storage devices with high performance. Broader contextThe hybrid electrodes of SWCNT/conducting polymer display high energy density due to pseudocapacitance originating from the conducting polymer. However, their power density is dramatically reduced in comparison with pure SWCNT-based electrodes, due to the poor electrical conductivity of PANI layers and overlapped PANI-PANI contact. Therefore, one of the most critical aspects in the development of SWCNT/conducting polymer supercapacitors is to optimize the energy density without deteriorating their high power capability as these two parameters determine concomitantly the ultimate performance of the supercapacitor. In this work, we report a ''skeleton/skin'' strategy to prepare free-standing, thin and flexible SWCNT/PANI hybrid films by a simple in situ electrochemical polymerization method using directly grown SWCNT films with continuous reticulate structure as template. The high electrical conductivity and flexibility, in combination with continuous porous architecture, suggest that as-prepared ultrathin freestanding SWCNT/PANI hybrid films have significant potential as promising electrode materials for thin, lightweight and flexible energy storage devices with high performance. The flexible supercapacitors based on the SWCNT/PANI hybrid films achieve high energy and power densities. 8726
Free-standing, hierarchical reticulate single-walled carbon nanotube (SWCNT) fi lms are embedded in poly(dimethylsiloxane) (PDMS) to fabricate stretchable conductors (SWCNT/PDMS stretchable conductors). The stretchable conductors are highly transparent in visible light region and retain excellent conductance under large tensile strains. Strain tests reveal a unique strainhistory dependence behavior of the resistance, and resistance stabilization is achieved upon repetitive stretching and releasing, implying that the SWCNT/ PDMS stretchable conductors can be programmed to be reversibly stretched to a defi ned strain without resistance changes. A quantitative description of the increase in resistance is determined by adopting the Weibull distribution. Moreover, a light-emitting diode is illuminated using a repetitively stretched SWCNT/PDMS strip as the connecting wire, demonstrating the utility of the stretchable conductors as interconnects for stretchable electronics. Because of the high transparency, high conductivity, and excellent stretchability, in addition to the facile fabrication, the SWCNT/PDMS stretchable conductors might be widely used as interconnects and electrodes for stretchable intelligent and functional devices.
wileyonlinelibrary.comRecent development in epidermal and bionic electronics systems has promoted the increasing demand for supercapcacitors with micrometer-thickness and good compatibility. Here, a highly flexible free-standing epidermal supercapacitor (SC-E) with merely 1 μm thickness and high performance is developed. Single-walled carbon nanotube/poly(3,4-ethylenedioxythiophene) hybrid films with unique inner-connected reticulation are adopted as electrodes for ultrathin structure and high electric conductivity. Then, based on two substrates with different surface energies, a stepwise lift-off method is presented to peel off the ultrathin integrated supercapacitor from the substrates nondestructively. As a result of the high conductive hybrid electrodes and the thin electrolyte layer, the as-designed supercapacitors (based on the total mass of two electrodes) achieve a good capacitance of 56 F g −1 and a superhigh power density of 332 kW kg −1 , which manifest superior performance in contrast to the other devices fabricated by traditional electrodes. Meanwhile, the ultrashort response time of 11.5 ms enables the epidermal supercapacitor (SC-E) work for high-power units. More importantly, the free-standing structure and outstanding flexibility (10 5 times bending) endow the SC-E with excellent compatibility to be integrated and work in the next generation of smart and epidermal systems.
The surface interaction of a well-characterized time modulated radio frequency (RF) plasma jet with polystyrene, poly(methyl methacrylate) and poly(vinyl alcohol) as model polymers is investigated. The RF plasma jet shows fast polymer etching but mild chemical modification with a characteristic carbonate ester and NO formation on the etched surface. By varying the plasma treatment conditions including feed gas composition, environment gaseous composition, and treatment distance, we find that short lived species, especially atomic O for Ar/1% O 2 and 1% air plasma and OH for Ar/1% H 2 O plasma, play an essential role for polymer etching. For O 2 containing plasma, we find that atomic O initiates polymer etching and the etching depth mirrors the measured decay of O atoms in the gas phase as the nozzlesurface distance increases. The etching reaction probability of an O atom ranging from 10 −4 to 10 −3 is consistent with low pressure plasma research. We also find that adding O 2 and H 2 O simultaneously into Ar feed gas quenches polymer etching compared to adding them separately which suggests the reduction of O and OH density in Ar/O 2 /H 2 O plasma.
Catalyst enhancement by atmospheric pressure plasma is a recently emerging field of research that embodies a complex system of reactive species and how they interact with surfaces. In this work we use an atmospheric pressure plasma jet integrated with a nickel on Al2O3/SiO2 support catalyst material to decompose methane gas by partial oxidation reaction. We use Fourier-transform Infrared spectroscopy analysis of the gas phase post reaction to measure the loss of methane and the production of CO, CO2, and H2O and diffuse reflectance Fourier-transform Infrared spectroscopy (DRIFTs) in situ analysis of the catalyst surface as a function of both catalyst temperature and plasma operating parameters. We find reduction of methane by both plasma alone, catalyst alone, and an increase when both plasma and catalyst were simultaneously used. The production of CO appears to be due primarily to the plasma source as it only appears above 2.5 W plasma dissipated power and decreases as catalyst temperature increases. CO2 production is enhanced by having the catalyst at high temperature and H2O production depends on both plasma power and temperature. Using DRIFTs we find that both heating and plasma treatment remove absorbed water on the surface of the catalyst. Plasma treatment alone however leads to the formation of CO and another IR spectral feature at 1590 cm−1, which may be attributed to carboxylate groups, bonded to the catalyst surface. These species exhibit a regime of plasma treatment where they are formed on the surface and where they are significantly removed from the catalyst surface. We see the formation of a new spectral feature at 995 cm−1 and discuss the behavior and possible origins of this feature. This research highlights the potential for plasma regeneration of catalyst materials as well as showing enhancement of the catalytic behavior under low temperature plasma treatment.
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