One of the most important drawbacks of classical and new advanced functional materials for applications outdoors, or in environments with high UV irradiation, is the light induced damage that reduces drastically their effective operation lifetime or durability. This makes protecting light sensitive materials against UV irradiation a nowadays important technological demand in almost every industrial field. This tutorial review incorporates the main aspects of UV damage to materials and describes the recently developed highly effective thin UV-protective coatings, based on UV-absorber molecules entrapped in a Sol-Gel derived ormosil matrix.

Aims. Metis is the first solar coronagraph designed for a space mission and is capable of performing simultaneous imaging of the off-limb solar corona in both visible and UV light. The observations obtained with Metis aboard the Solar Orbiter ESA-NASA observatory will enable us to diagnose, with unprecedented temporal coverage and spatial resolution, the structures and dynamics of the full corona in a square field of view (FoV) of ±2.9 • in width, with an inner circular FoV at 1.6 • , thus spanning the solar atmosphere from 1.7 R to about 9 R , owing to the eccentricity of the spacecraft orbit. Due to the uniqueness of the Solar Orbiter mission profile, Metis will be able to observe the solar corona from a close (0.28 AU, at the closest perihelion) vantage point, achieving increasing out-of-ecliptic views with the increase of the orbit inclination over time. Moreover, observations near perihelion, during the phase of lower rotational velocity of the solar surface relative to the spacecraft, allow longer-term studies of the off-limb coronal features, thus finally disentangling their intrinsic evolution from effects due to solar rotation. Methods. Thanks to a novel occultation design and a combination of a UV interference coating of the mirrors and a spectral bandpass filter, Metis images the solar corona simultaneously in the visible light band, between 580 and 640 nm, and in the UV H i Lyman-α line at 121.6 nm. The visible light channel also includes a broadband polarimeter able to observe the linearly polarised component of the K corona. The coronal images in both the UV H i Lyman-α and polarised visible light are obtained at high spatial resolution with a spatial scale down to about 2000 km and 15000 km at perihelion, in the cases of the visible and UV light, respectively. A temporal resolution down to 1 second can be achieved when observing coronal fluctuations in visible light. Results. The Metis measurements, obtained from different latitudes, will allow for complete characterisation of the main physical parameters and dynamics of the electron and neutral hydrogen/proton plasma components of the corona in the region where the solar wind undergoes the acceleration process and where the onset and initial propagation of coronal mass ejections (CMEs) take place. The near-Sun multi-wavelength coronal imaging performed with Metis, combined with the unique opportunities offered by the Solar Orbiter mission, can effectively address crucial issues of solar physics such as: the origin and heating/acceleration of the fast and slow solar wind streams; the origin, acceleration, and transport of the solar energetic particles; and the transient ejection of coronal mass and its evolution in the inner heliosphere, thus significantly improving our understanding of the region connecting the Sun to the heliosphere and of the processes generating and driving the solar wind and coronal mass ejections. Conclusions. This paper presents the scientific objectives and requirements, the overall optical design of the Metis instrument, t...

Aims. This paper describes the Polarimetric and Helioseismic Imager on the Solar Orbiter mission (SO/PHI), the first magnetograph and helioseismology instrument to observe the Sun from outside the Sun-Earth line. It is the key instrument meant to address the top-level science question: How does the solar dynamo work and drive connections between the Sun and the heliosphere? SO/PHI will also play an important role in answering the other top-level science questions of Solar Orbiter, as well as hosting the potential of a rich return in further science. Methods. SO/PHI measures the Zeeman effect and the Doppler shift in the Fe i 617.3 nm spectral line. To this end, the instrument carries out narrow-band imaging spectro-polarimetry using a tunable LiNbO 3 Fabry-Perot etalon, while the polarisation modulation is done with liquid crystal variable retarders (LCVRs). The line and the nearby continuum are sampled at six wavelength points and the data are recorded by a 2k × 2k CMOS detector. To save valuable telemetry, the raw data are reduced on board, including being inverted under the assumption of a Milne-Eddington atmosphere, although simpler reduction methods are also available on board. SO/PHI is composed of two telescopes; one, the Full Disc Telescope (FDT), covers the full solar disc at all phases of the orbit, while the other, the High Resolution Telescope (HRT), can resolve structures as small as 200 km on the Sun at closest perihelion. The high heat load generated through proximity to the Sun is greatly reduced by the multilayer-coated entrance windows to the two telescopes that allow less than 4% of the total sunlight to enter the instrument, most of it in a narrow wavelength band around the chosen spectral line. Results. SO/PHI was designed and built by a consortium having partners in Germany, Spain, and France. The flight model was delivered to Airbus Defence and Space, Stevenage, and successfully integrated into the Solar Orbiter spacecraft. A number of innovations were introduced compared with earlier space-based spectropolarimeters, thus allowing SO/PHI to fit into the tight mass, volume, power and telemetry budgets provided by the Solar Orbiter spacecraft and to meet the (e.g. thermal) challenges posed by the mission's highly elliptical orbit.

UV-protective coatings have been prepared by the sol-gel method, to reduce the destructive effects of UV radiation on easily photodegradable devices, i.e. those containing organic compounds, such as dyes and pigments or plastic materials to be used in outdoor applications. A benzophenone derivative (2,2-dihydroxy, 4-methoxybenzophenone), showing high photostability and strong absorption in the UV range, was embedded in an ormosil matrix. The usage of an organically modified silica matrix enhances the solubility of the UV absorber in the matrix allowing the preparation of highly loaded coatings. The protective coatings, prepared at room temperature, require no thermal treatment after deposition, allowing therefore their application on temperature sensitive materials. The resulting films have a strong absorption in the UV range with a thickness of only 1.0 mm. In addition, the UV-absorbing coatings are transparent, colourless, and exhibit high optical quality. The UV-protective coatings offer an easy method to prevent the photodegradation of organic materials without altering their optical properties in the visible region.Fluorescent rhodamine dye-doped thin ormosil films were coated with a UV-protective layer in order to study their effectiveness in the reduction of the photodegradation of the dye upon irradiation with UV light. The degradation of 20% of the molecules in coated samples was 14 times slower than that of the uncoated samples. The effective temperature range of the UV-protective coatings was established by measuring the photodegradation of the samples at different temperatures.

No abstract

No abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

Although there are excellent contributions in the scientific literature covering most aspects of sol‐gel hybrid materials for optics and electro‐optics, this short review shall concentrate on the research activities of the Sol‐Gel Group (SGG) at Madrid in this field, describing recent progress and interdisciplinary approaches to materials with novel properties.