Water quality was monitored in Boreal Shield lakes for 3 years following their simultaneous impact by clearcut logging or wildfire. Seventeen similar undisturbed lakes served as references. Dissolved organic carbon (DOC) and the light attenuation coefficient (εPAR) were up to threefold higher in cut lakes than in reference and burnt lakes. Compared with median values for reference lakes, cut and burnt lakes had higher concentrations of total phosphorus (TP) (two- to three-fold), total organic nitrogen (TON) (twofold), and K+, Cl-, and Ca2+ (up to sixfold). NO3- and SO42- concentrations were up to 60- and 6-fold higher, respectively, in burnt lakes than in reference and cut lakes. In most cases, impacts were directly proportional to the area harvested or burnt divided by the lake's volume or area. These simple models correctly predicted the changes observed in three lakes harvested during the study. Some of the ob served effects occur on different time scales. Mobile ions released by fire (K+, Cl-, SO42-, NO3-) or harvesting (K+, Cl-, some DOC) are rapidly flushed out of the watershed (50% decrease in 3 years). Other constituents or properties (TP, TON, DOC, εPAR, Ca2+, Mg2+) show little change or are still increasing after 3 years and will take a longer time to reach normal levels.

Element export rates from the drainage area of nine harvested, nine burnt, and 16 reference Boreal Shield lake basins in Haute-Mauricie, Québec, were estimated for the 3 years following harvesting or fires. Export rates from the drainage area of the basins were evaluated using lake sampling surveys, estimated hydrological budgets, and estimated nutrient retention during lake transit. Increases in K + , total N, and total P export rates were similar between harvested and burnt drainage areas. However, harvested drainage areas exported more dissolved organic C, while burnt drainage areas exported more Mg 2+ , NO 3 -, and SO 4 2-. Potassium cumulative losses in runoff during the 3 years of the study were of a similar magnitude as volatilization losses during fires and corresponded to -33% of the losses by biomass removal during harvesting. While the increased export rates for N and P following fires or harvesting represented negligible losses of nutrients for the forest, they were important supplementary inputs to lakes. The differences in element export rates observed between harvested and burnt drainage areas indicate that these disturbances have different impacts on biogeochemical cycles in the Boreal Shield forest.

For 30 Canadian Shield lakes of southeastern Quebec, catchment slope and lake morphometry account for 50-70% of the variability of chlorophyll a (Chl a), dissolved organic carbon (DOC), total phosphorus (TP), NO3- , and NH4+ . Dissolved organic carbon, TP, Chl a, Ca, and Mg are negatively related to catchment slope, whereas NO3- and NH4+ increase with increasing slope. Concentrations of more conservative constituents (SO42-, Na, K) increase with decreasing elevation as a result of higher evapotranspiration and lower precipitation at low elevations. Catchment variables (slope, drainage area, percent wetlands) are as good predictors of Chl a (r2 = 0.7) as are water chemistry variables (TP, Ca, Mg, and pH). Dominant vegetation (deciduous vs. coniferous) has little or no influence on lake water chemistry. Hydrogeological data for the Canadian Shield suggest that, during periods of high runoff, the development of waterlogged areas and the importance of overland flow on saturated soils are inversely proportional to catchment slope. We propose that the strong influence of catchment slope on water quality is due to slope-dependent seasonal waterlogging, which determines the fate (retention or export to surface waters) of dissolved substances produced within and moving through the forest floor.

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