Several hydrothermal deposits associated with ultramafic rocks have recently been found along slow spreading ridges with a low magmatic budget. Three preferential settings are identified: (1) rift valley walls near the amagmatic ends of ridge segments; (2) nontransform offsets; and (3) ultramafic domes at inside corners of ridge transform-fault intersections. The exposed mantle at these sites is often interpreted to be a detachment fault. Hydrothermal cells in ultramafic rocks may be driven by regional heat flow, cooling gabbroic intrusions, and exothermic heat produced during serpentinization. Along the Mid-Atlantic Ridge (MAR), hydrothermal deposits in ultramafic rocks include the following: (1) sulfide mounds related to high-temperature low-pH fluids (Logatchev, Rainbow, and Ashadze); (2) carbonate chimneys related to low-temperature, high-pH fluids (Lost City); (3) low-temperature diffuse venting and high-methane discharge associated with silica, minor sulfides, manganese oxides, and pervasive alteration (Saldanha); and (4) stockwork quartz veins with sulfides at the base of detachment faults (15°05′N). These settings are closely linked to preferential circulation of fluid along permeable detachment faults. Compared to mineralization in basaltic environments, sulfide deposits associated with ultramafic rocks are enriched in Cu, Zn, Co, Au, and Ni. Gold has a bimodal distribution in low-temperature Zn-rich and in hightemperature Cu-rich mineral assemblages. The Cu-Zn-Co-Au deposits along the MAR seem to be more abundant than in ophiolites on land. This may be because ultramafic-hosted volcanogenic massive sulfide deposits on slow spreading ridges are usually not accreted to continental margins during obduction and may constitute a specific marine type of mineralization.

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Massive ore-grade zinc, copper and iron sulphide deposits have been found at the axis of the East Pacific Rise. Although their presence on the deep ocean-floor had been predicted rhere was no supporting observational euidence. The East Pacific Rise deposits represent a modern analogue of Cyprus-type sulphide ores associated with ophiolitic rocks on land. They contain at least 29% zinc meral and 6 % merallic copper. Their discovery will prouide a new focus for deep-sea exploration, leading to new assessmenrs of the concentration of metals in the upper layers of the oceanic crust.-THE area of the deposits of ore-grade zinc, copper and iron sulphide was explored and sampled in February-March 1978 by the manned diving saucer CYANA during the expedition CYAMEXi. The expedition, the only submersible diving programme that has so far been conducted on the East Pacific Rise (EPR), is part of the French-American-Mexican project RITA (Rivera-Tamayo), a 3-yr study devoted to detailed geological and geophysical investigations of the EPR crest. The ore deposits were sampled in water depths of close to 2,620 m a t two neighbouring sites near 20" 54' N 109" 03'W. (refs 2-5) about 9 0 km north of the Rivera transform fault and 240 km south of the Tamayo transform fault (Fig. 1). Three dives of Cyana (CY 78-06, 08 and 12) crossed the two sampling sites, and we collected samples during two of these dives (CY 78-08 and 12). However, during al1 dives in the EPR axial zone, signs of hydrothermal activity were seen, including colonies of dead giant clams, fields of pillow lavas with pronounced colourstaining at the base of pillows, and coloured deposits on exposed scarp surfaces of normal faults and open fissures'. Coral-like growths, possibly of native sulphur, occur in other locations, including a sedimented fault-scarp about 1.0 km to the West of where the sulphide ores were sampled. Sampling sites The two sites where the sulphides were sampled lie on the lightly sedimented flanks of steep-sided structural depressions, about 20-30 m deep, 20-30 m wide. and about 600-700 m west of the axis of the 'extrusion zone' where the youngest lavas occur. Whereas the extrusion zone is marked by a 50 m-high sedimentfree discontinuous ridge with n o fissures or faults, the structural *The authors are al1 members of the CYAMEX Scientific Team.

Richly decorated enamelled glass objects and fragments of different provenance and epoch have been analysed using mobile and fixed Raman instruments: some fragments of the outstanding Begram treasure (Musée des arts asiatiques -Guimet, Paris) dated to the 1 st century AD, mosque lamps and bottles of Syrian/Egyptian provenance dated to the 13 th /14 th century (collections of Musée du Louvre and of Musée des arts décoratifs, Paris). The techniques are compared using the data obtained from the study of a group of similar objects and fragments discovered in Melfi Castle in the South of Italy in an archaeological context dated to the last quarter of the 13 th century. The glass body was difficult to analyse requiring the use of high-energy high-power laser beams and/or sampling that allowed determining the soda-lime type precisely. In contrast, a variety of colouring agents was identified: lapis lazuli and/or cobalt for blue, antimonate pyrochlore solid solution for yellow, with the addition of cobalt/lapis lazuli for green, hematite for red and calcium phosphate/cassiterite/calcium antimonate for white. Where present, gilding was found applied on a rough and matt red enamel base probably in order to guarantee the physical adherence of the gold leaves. The comparison between the above mentioned groups of objects and between them and data existing in the literature about Roman enamelled glass allowed us to follow the evolution of the technology of this class of precious artefacts and to discuss the potential of the mobile Raman analysis.

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