A quantum anharmonic oscillator is defined by the Hamiltonian H = − d 2 dx 2 + V (x), where the potential is given byUsing the Sinc collocation method combined with the double exponential transformation, we develop a method to efficiently compute highly accurate approximations of energy eigenvalues for anharmonic oscillators. Convergence properties of the proposed method are presented. Using the principle of minimal sensitivity, we introduce an alternate expression for the mesh size for the Sinc collocation method which improves considerably the accuracy in computing eigenvalues for potentials with multiple wells.We apply our method to a number of potentials including potentials with multiple wells. The numerical results section clearly illustrates the high efficiency and accuracy of the proposed method. All our codes are written using the programming language Julia and are available upon request.

Abstract. Sturm-Liouville problems are abundant in the numerical treatment of scientific and engineering problems. In the present contribution, we present an efficient and highly accurate method for computing eigenvalues of singular Sturm-Liouville boundary value problems. The proposed method uses the double exponential formula coupled with Sinc collocation method. This method produces a symmetric positive-definite generalized eigenvalue system and has exponential convergence rate. Numerical examples are presented and comparisons with single exponential Sinc collocation method clearly illustrate the advantage of using the double exponential formula.

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In this work, we propose a method combining the Sinc collocation method with the double exponential transformation for computing the eigenvalues of the anharmonic Coulombic potential. We introduce a scaling factor that improves the convergence speed and the stability of the method. Further, we apply this method to Coulombic potentials leading to a highly efficient and accurate computation of the eigenvalues.

In the present contribution, we apply the double exponential Sinc-collocation method (DESCM) to the one-dimensional time independent Schrödinger equation for a class of rational potentials of the form V (x) = p(x)/q(x). This algorithm is based on the discretization of the Hamiltonian of the Schrödinger equation using Sinc expansions. This discretization results in a generalized eigenvalue problem where the eigenvalues correspond to approximations of the energy values of the corresponding Hamiltonian. A systematic numerical study is conducted, beginning with test potentials with known eigenvalues and moving to rational potentials of increasing degree.