The presence of a straw mulch on the soil surface did not significantly affect the persistence of metribuzin [4-amino-6-tert-butyl-3-(methylthio)-as-triazin-5 (4H)-one] in the soil. The half-life of metribuzin was 5.3 days in 1979 and 12.5 days in 1980 in the field when the time the herbicide was exposed on the soil and straw surface prior to rainfall or irrigation was 10 and 0 days, respectively. The half-life of metribuzin was 17.1 days in the greenhouse where soil temperature was lower and leaching, volatilization, and photodegradation losses were less than in the field. Increasing the amount of straw on the soil surface greatly decreased the initial soil reception of metribuzin as well as the amount of metribuzin that was subsequently washed off the straw by water. Less than 45% of the applied metribuzin reached the soil surface when 2250 kg/ha of straw was present and 0.3 cm or more of water was applied.
Acetochlor [2-chloro-N-(ethoxymethyl)-N-(2-ethyl-6-methylphenyl)acetamide], alachlor [2-chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)acetamide], and metolachlor [2-chloro-N-(2-ethyl-6-methylphenyl)-N-(2-methoxy-1-methylethyl)acetamide] were applied in 280 L of water/ha to plots covered with 0 to 6720 kg/ha of wheat (Triticum aestivumL.) straw. At straw levels of 1120 kg/ha or greater, 50% or less of the applied herbicides were received by the soil surface before irrigation. Sprinkle irrigation (1.3 cm) washed 15 to 20% of the originally applied herbicide into the soil regardless of straw level. More metolachlor was retained on the straw than acetochlor or alachlor. Analysis of the wheat straw indicated that little water-extractable herbicide remained for all herbicides. Initial herbicidal activity on grain sorghum [Sorghum bicolor(L.) Moench.] was reduced by the presence of wheat straw at the time of application, with acetochlor being least affected and alachlor most affected. Ten days after treatment, less than 10% of the original alachlor and acetochlor remained in the soil. When planted at this time, grain sorghum response was inversely related to the amount of straw mulch that was originally present. Metolachlor residues in the soil on day 10 were 11 to 26% of that on day 0 and there was comparably less reduction in activity on grain sorghum.
Field studies were conducted to determine if varying carrier volume proportionally with herbicide dosage, thus maintaining constant herbicide concentration in the carrier, would change the response of sweet corn to glyphosate and of cotton to 2,4-D when compared with using a constant carrier volume where herbicide concentration would vary and be more dilute. For all the parameters measured, more sweet corn injury occurred if the concentration of glyphosate was constant in all volumes of spray. The glyphosate no-effect level for sweet corn was determined to be 0.046 kg/ha when using the variable carrier volume but was over four times greater (0.185 kg/ha) when applied at the constant carrier volume of 281 L/ha. Cotton response to 2,4-D was similar, with the constant herbicide concentration in the carrier at the lower volumes causing greater injury. The response of seed cotton yield was not different when comparing constant to variable carrier volume. The highly sensitive growth stage of cotton at the time of application (bud formation before blooming) may explain this result. These studies demonstrate the need to use carrier volumes that are proportional to the herbicide dosage, thus maintaining constant herbicide concentration in the carrier, when conducting simulated herbicide drift research. Failure to do so could underestimate the potential for injury.
Experiments to determine effects of chlorimuron, clomazone, and imazaquin applied the year before planting corn, cotton, and sorghum were conducted at three locations in Georgia. Corn injury was <20% in 1987 and 1988 and yield was not affected. In 1988, imazaquin applied at a high rate or sequentially the previous year to late-planted soybeans injured corn more than applications to the early-planted soybeans. Cotton was the most sensitive crop to herbicides applied the previous year. However, seed cotton yield was not decreased due to herbicides applied the previous year. Sorghum growth and yield 8 weeks after planting was not affected by soybean herbicide application the previous year. Sicklepod, corn, and wheat bioassays did not detect any of the herbicides in soil samples obtained the season after treatment. Bioassays accurately predicted potential injury in corn and sorghum but not cotton.
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