The reaction D2+HCl=HD+DCl has been investigated at temperatures from 765°K to 843°K. The reaction is almost entirely homogeneous, and, up to temperatures of the order of 830°K, bimolecular. The fraction which proceeds heterogeneously is determined in a vessel packed with tubes. The constant of the homogeneous bimolecular reaction can be represented by the following equation: Ko=6.27×1013×T12×e−26.200/T mole−1 cm3 sec.−1.At the maximum measured temperature of 843°K deviations were noticed which may have been due to atomic reaction.
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