Anti-icing surfaces have a critical footprint on daily lives of humans ranging from transportation systems and infrastructure to energy systems, but creation of these surfaces for low temperatures remains elusive. Non-wetting surfaces and liquid-infused surfaces have inspired routes for the development of icephobic surfaces. However, high freezing temperature, high ice adhesion strength, and high cost have restricted their practical applications. Here we report new magnetic slippery surfaces outperforming state-of-the-art icephobic surfaces with a ice formation temperature of −34 °C, 2–3 orders of magnitude higher delay time in ice formation, extremely low ice adhesion strength (≈2 Pa) and stability in shear flows up to Reynolds number of 105. In these surfaces, we exploit the magnetic volumetric force to exclude the role of solid–liquid interface in ice formation. We show that these inexpensive surfaces are universal and can be applied to all types of solids (no required micro/nano structuring) with no compromise to their unprecedented properties.
Scale formation is a common problem in a wide range of industries such as oil and gas, water desalination, and food processing. Conventional solutions for this problem including mechanical removal and chemical dissolution are inefficient, costly, and sometimes environmentally hazardous. Surface modification approaches have shown promises to address this challenge. However, these approaches suffer from intrinsic existence of solid-liquid interfaces leading to high rate of scale nucleation and high adhesion strength of the formed scale. Here, we report a new surface called magnetic slippery surface in two forms of Newtonian fluid (MAGSS) and gel structure (Gel-MAGSS). These surfaces provide a liquid-liquid interface to elevate the energy barrier for scale nucleation and minimize the adhesion strength of the formed scale on the surface. Performance of these new surfaces in both static and dynamic (under fluid flow) configurations is examined. These surfaces show superior antiscaling properties with an order of magnitude lower scale accretion compared to the solid surfaces and offer longevity and stability under high shear flow conditions. We envision that these surfaces open a new path to address the scale problem in the relevant technologies.
Evaporation is a fundamental and core phenomenon in a broad range of disciplines including power generation and refrigeration systems, desalination, electronic/photonic cooling, aviation systems, and even biosciences. Despite its importance, the current theories on evaporation suffer from fitting coefficients with reported values varying in a few orders of magnitude. Lack of a sound model impedes simulation and prediction of characteristics of many systems in these disciplines. Here, we studied evaporation at a planar liquid-vapor interface through a custom-designed, controlled, and automated experimental setup. This experimental setup provides the ability to accurately probe thermodynamic properties in vapor, liquid, and close to the liquid-vapor interface. Through analysis of these thermodynamic properties in a wide range of evaporation mass fluxes, we cast a predictive model of evaporation based on nonequilibrium thermodynamics with no fitting parameters. In this model, only the interfacial temperatures of liquid and vapor phases along with the vapor pressure are needed to predict evaporation mass flux. The model was validated by the reported study of an independent research group. The developed model provides a foundation for all liquid-vapor phase change studies including energy, water, and biological systems.
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