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The development of alkali-activated materials (AAMs) as an alternative to Portland cement (PC) has seen significant progress in the past decades. However, there still remains significant uncertainty regarding their long term performance when used in steel-reinforced structures. The durability of AAMs in such applications depends strongly on the corrosion behaviour of the embedded steel reinforcement, and the experimental data in the literature are limited and in some cases inconsistent. This letter elucidates the role of the chemistry of AAMs on the mechanisms governing passivation and chloride-induced corrosion of the steel reinforcement, to bring a better understanding of the durability of AAM structures exposed to chloride. The corrosion of the steel reinforcement in AAMs differs significantly from observations in PC; the onset of pitting (or the chloride 'threshold' value) depends strongly on the alkalinity, and the redox environment, of these binders. Classifications or standards used to assess the severity of steel corrosion in PC appear not to be directly applicable to AAMs due to important differences in pore solution chemistry and phase assemblage.

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Ordinary Portland cement (OPC) is the dominant binder in the construction industry with a global production that currently reaches a total of 3 Gt per year. As a consequence, the cement industry's contribution to the total worldwide CO 2 emissions is of about 7% of the total emissions. Publications on the field of alkali-activated binders (also termed geopolymers), state that this new material is, potentially, likely to become an alternative to Portland cement. However, recent LCA studies show that the environmental performance of alkali-activated binders depends, to great extent, of their composition. Also, researchers report that these binders can be produced in a more eco-efficient manner if the use of sodium silicate is avoided. This is due to the fact that the referred component is associated to a high carbon footprint. Besides, most alkali-activated cements suffer from severe efflorescence, a reaction originated by the fact that the alkaline and/or soluble silicates that are added during processing cannot be totally consumed. This paper presents experimental results on hybrid alkaline cements. The compressive strength results and the efflorescence observations show that some of the new mixes already exhibit a promising performance.