The interaction of a laser-induced cavitation bubble with an elastic boundary and its dependence on the distance between bubble and boundary are investigated experimentally. The elastic boundary consists of a transparent polyacrylamide (PAA) gel with 80% water concentration with elastic modulus E = 0.25 MPa. At this E-value, the deformation and rebound of the boundary is very pronounced providing particularly interesting features of bubble dynamics. It is shown by means of high-speed photography with up to 5 million frames s−1 that bubble splitting, formation of liquid jets away from and towards the boundary, and jet-like ejection of the boundary material into the liquid are the main features of this interaction. The maximum liquid jet velocity measured was 960 m s−1. Such high-velocity jets penetrate the elastic boundary even through a water layer of 0.35 mm thickness. The jetting behaviour arises from the interaction between the counteracting forces induced by the rebound of the elastic boundary and the Bjerknes attraction force towards the boundary. General principles of the formation of annular and axial jets are discussed which allow the interpretation of the complex dynamics. The concept of the Kelvin impulse is examined with regard to bubble migration and jet formation. The results are discussed with respect to cavitation erosion, collateral damage in laser surgery, and cavitation-mediated enhancement of pulsed laser ablation of tissue.

The interaction of a laser-induced cavitation bubble with an elastic boundary is investigated experimentally by high-speed photography and acoustic measurements. The elastic material consists of a polyacrylamide (PAA) gel whose elastic properties can be controlled by modifying the water content of the sample. The elastic modulus, E, is varied between 0.017 MPa and 2.03 MPa, and the dimensionless bubble–boundary distance, γ, is for each value of E varied between γ = 0 and γ = 2.2. In this parameter space, jetting behaviour, jet velocity, bubble migration and bubble oscillation time are determined. The jetting behaviour varies between liquid jet formation towards or away from the elastic boundary, and formation of an annular jet which results in bubble splitting and the subsequent formation of two very fast axial liquid jets flowing in opposite directions. The liquid jet directed away from the boundary reaches a maximum velocity between 300 ms−1 and 600 ms−1 (depending on the elastic modulus of the sample) while the peak velocity of the jet directed towards the boundary ranges between 400 ms−1 and 800 ms−1 (velocity values averaged over 1 μs). Penetration of the elastic boundary by the liquid jet is observed for PAA samples with an intermediate elastic modulus between 0.12 and 0.4 MPa. In this same range of elastic moduli and for small γ-values, PAA material is ejected into the surrounding liquid due to the elastic rebound of the sample surface that was deformed during bubble expansion and forms a PAA jet upon rebound. For stiffer boundaries, the bubble behaviour is mainly characterized by the formation of an axial liquid jet and bubble migration directed towards the boundary, as if the bubble were adjacent to a rigid wall. For softer samples, the bubble behaviour becomes similar to that in a liquid with infinite extent. During bubble collapse, however, material is torn off the PAA sample when bubbles are produced close to the boundary. We conclude that liquid jet penetration into the boundary, jet-like ejection of boundary material, and tensile-stress-induced deformations of the boundary during bubble collapse are the major mechanisms responsible for cavitation erosion and for cavitation-enhanced ablation of elastic materials as, for example, biological tissues.

Garnet is one of the most robust and ubiquitous minerals that record element zoning during crustal metamorphism. In addition to major elements, zoning in trace elements can provide a wealth of information to document the changing conditions of garnet growth and modification. However, mapping trace elements at low concentrations, over large areas and with high resolution has remained a major challenge.We present a comprehensive investigation of the TE distribution in garnet from three Alpine samples that underwent a complex evolution at different metamorphic conditions. The TE distribution in garnet grains is mapped in 2D in thin section with a novel approach using laser ablation inductively coupled plasma time of flight mass spectrometry (LA-ICP-TOFMS) to achieve a lateral resolution of 5 µm and limits of detection for the heavy rare earth elements (REE) down to 0.2 µg/g. Comparison with major element zoning measured by electron probe micro-analysis (EPMA) and trace elements measured by conventional LA-ICPMS spot analysis testifies to the accuracy of the measurements.Garnet in an amphibolite-facies metapelite from Campolungo, Central Alps that recorded metamorphism to 600°C preserves Y+REE trace element zoning that closely matches that of Ca. In this sample, there is no notable diffusive modification for trace elements. Y+REE zoning is dominated by Rayleigh fractionation in the core and by the sporadic breakdown of accessory phases producing annuli in the rim of the garnet.A granulite-facies garnet from Malenco, Eastern Central Alps, formed during subsolidus heating, followed by peritectic melting reactions up to temperatures of 800-850°C. Major and trace element zoning are decoupled indicating diffusional resetting of major elements, whereas trace elements still largely document the growth history. Enrichment of trace elements in the garnet mantle may be related to the consumption of biotite (V, Cr) and the dissolution of zircon (Zr) and monazite (Y+REE) in the melt. Diffusion of Y+HREE at the core-mantle boundary occurred over a length scale of ~200 µm.Garnet in an eclogite from the Sesia Zone, Western Alps (P~2 GPa, T~600°C) displays pronounced fluid-related veinlets, visible in FeO, MgO and MnO, which cross-cut the primary growth zoning. Surprisingly, complex Y+REE and Cr zoning is not affected by the veinlets, indicating that they did not form by a crack-seal mechanism but are rather related to a selective replacement process.The trace element maps provide a detailed insight into the growth and modification of garnet and thus allow assessment of equilibrium versus disequilibrium processes, and assist in determination of P-T conditions, garnet dating, diffusion modelling as well as documenting fluid-induced modifications.

A new software control system enables adaptable and task-specific ablation modes for LA-ICP-TOFMS imaging.

The last decade witnessed considerable progress in the development of laser ablation/ionisation time-of-flight mass spectrometry (LI-TOFMS). The improvement of both the laser ablation ion sources employing femtosecond lasers and the method of ion coupling with the mass analyser led to highly sensitive element and isotope measurements, minimisation of matrix effects, and reduction of various fractionation effects. This improvement of instrumental performance can be attributed to the progress in laser technology and accompanying commercialisation of fs-laser systems, as well as the availability of fast electronics and data acquisition systems. Application of femtosecond laser radiation to ablate the sample causes negligible thermal effects, which in turn allows for improved resolution of chemical surface imaging and depth profiling. Following in the footsteps of its predecessor ns-LIMS, fs-LIMS, which employs fs-laser ablation ion sources, has been developed in the last two decades as an important method of chemical analysis and will continue to improve its performance in subsequent decades. This review discusses the background of fs-laser ablation, overviews the most relevant instrumentation and emphasises their performance figures, and summarizes the studies on several applications, including geochemical, semiconductor, and bio-relevant materials. Improving the chemical analysis is expected by the implementation of laser pulse sequences or pulse shaping methods and shorter laser wavelengths providing current progress in mass resolution achieved in fs-LIMS. In parallel, advancing the methods of data analysis has the potential of making this technique very attractive for 3D chemical analysis with micrometre lateral and sub-micrometre vertical resolution.