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Arsenopyrite (FeAsS), gudmundite (FeSbS) and the rarer Fe sulfosalts berthierite (FeSb2S4) and garavellite (FeSbBiS4), were investigated by Raman spectroscopy. Whereas (Sb,Bi)S3 pyramids are responsible for the Raman spectra of berthierite and garavellite, the spectra of gudmundite and arsenopyrite arise from the stretching and bending modes of (Sb,As)S units. Internal vibrations for berthierite and garavellite occur between 400 and 50 cm–1, and those of the gudmundite and arsenopyrite between 500 and 100 cm–1. The longer bond distances of the SbS3 groups readily explain the lower frequencies for berthierite in comparison with garavellite. Similarly, the greater mass and the longer bond distances of the Sb–S units also explain the lower frequencies observed for gudmundite relative to arsenopyrite.

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Antimony-and Pb-Sb-quartz veins from the Bragança district, Portugal, are mainly hosted by

The authors have prepared a detailed map of Slovakia's ecosystems, which identifies individual ecosystems and their spatial distribution, status, and selected properties. The impetus for the production of this map is the need of various stakeholders, especially nature protection bodies, forestry management, agricultural management and public administration, for better data on the distribution of ecosystems. The methodology mostly involves using GIS analytical tools to combine datasets on nature protection, forestry, and agriculture which list attributes related to habitat identification. The results can be used for ecosystem services assessment, spatial planning, nature protection analysis, and other related purposes. The spatial precision of the data is determined by that of the field data, which was mostly created at scales between 1:10000 and 1:5000. The data are stored in the form of a geodatabase containing more than 1,000,000 polygons.

This study compared morphological characteristics and seed germinative capabilities of the metallophyte Arabidopsis arenosa grown at a copper mining heap with individuals of the same species grown at a reference site. We observed the height of the plant, the width of rosette leaves at ground level, the width and length of the lowest stem leaf, the number of seeds per silique, the below-ground biomass weight and the above-ground biomass weight. We found that the pH and the Eh of soil taken from the root sphere of A. arenosa were similar on both sites, and the pH ranged from 5.87 on the heap to 7.03 on the reference site. The measured morphological attributes and the number of seeds produced were significantly reduced (p < 0.01) in plants from the metalliferous site. The biggest difference was in leaf length, where plants from the heap were almost 2.5-times smaller. The mean germinative capacity of seeds ranged from 87% to 93%, and was not different between sites. The length of roots of germinated seeds from the heap (9.14 mm) was significantly longer than those from the reference site (8.27 mm). Results support the hypothesis of the influence of site conditions and heavy metals on the habitus of the plant and its development.

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