BACKGROUNDThere is a need to help farmers and industries develop value‐added composite and nanocomposite materials from agricultural residuals. Cellulose nanofibers (CNFs) were made using a TEMPO oxidation method and celluloses were prepared by acid–base method and extracting method, which were all from corn stalk, an agricultural residual. The prepared celluloses were dissolved separately in dimethylacetamide/LiCl solvent and CNFs were added at 0.0%, 0.5%, 1.5% and 3.0% to form all‐cellulose nanocomposites, and then cast into films. Morphology, structure and properties of the nanocomposite films were characterized using atomic force microscopy, field emission scanning electron microscopy, thermogravimetric analysis, X‐ray diffraction and mechanical testing.RESULTSThe all‐cellulose nanocomposite films with different cellulose matrices exhibited good optical transparency and layer structure. The all‐cellulose nanocomposite films with cellulose prepared by the extracting method (Composite E) exhibited a higher crystallinity, better thermal stability and higher mechanical strength compared to the all‐cellulose nanocomposite films with cellulose prepared by the acid–base method (Composite A).CONCLUSIONSThe crystal structure of the all‐cellulose nanocomposite films indicated the coexistence of cellulose I and cellulose II. However, in contrast to Composite A, the diffraction intensity of cellulose I in Composite E was higher than that of cellulose II. This was another reason that the mechanical properties of Composite E were superior to those of Composite A. In addition, the mechanical properties of the all‐cellulose nanocomposite films were significantly different when the addition of CNFs reached 3.0% by weight, as indicated by a multiple‐range comparison. © 2020 Society of Chemical Industry
Predicting and estimating the response of subway tunnel to adjacent excavation of foundation pit is a research focus in the field of underground engineering. Based on the principle of two-stage method and incremental method, an analytic approach is suggested in this paper to solve this problem in an accurate and rapid way, and the upheavals of tunnel due to adjacent excavation are solved by analytic method. Besides, the presented method is used in the practical engineering case of Shenzhen Metro Line 11 and verified by numerical simulation and in situ measurement. Finally, a parametric analysis is performed to investigate the influence of different factors on tunnel's deflection. Some useful conclusions have been drawn from the research as below: The deflection results of tunnel obtained from analytic method are nearly consistent with the results getting from numerical analysis and measured data, which verified the accuracy and rationality of presented method. The excavation size has a significant impact on both the displacement values and influenced range of tunnel. However, the relative distance only impacts the displacement values of tunnel, but not the influenced range of tunnel. It may provide certain reference to analyze the deflection of subway tunnel influenced by adjacent excavation.
To accelerate the high value-added usage of agricultural residue, cellulose and cellulose nanofibers (CNFs) were extracted from wheat straw and then formed into all-cellulose nanocomposite films. The acid–alkali method (AM) and the extraction method (EM) were respectively adopted to prepare wheat straw cellulose (WSC), and the TEMPO oxidation method was used to extract CNFs. The nanocomposite films were fabricated by dissolving WSC and adding different CNF contents of 0.0, 0.5, 1.5, and 3.0%. There was a better miscibility for the all-cellulose nanocomposite film prepared by EM (Composite-E) compared to that for the all-cellulose nanocomposite film prepared by AM (Composite-A). Composite-E also showed a better optical transparency than Composite-A. The thermal stability of the two RWSCs presented contrary results when the CNFs were added, indicating a higher thermal stability for Composite-E than for Composite-A. This should have determined the properties of the films in which Cellulose I and Cellulose II coexisted for the all-cellulose nanocomposite films, and the forming mechanism of Cellulose II and crystallinity were determined by the cellulose-extracting method. X-ray diffraction (XRD) and Fourier-transform infrared (FT-IR) spectroscopy also showed that there was more Cellulose I in Composite-E than in Composite-A. The results are expected to enrich the data for deep processing of agricultural residues.
In order to relieve the increasing ground traffic pressure in the process of urbanization in China, it is inevitable to build more metro lines. However, the stratum movement caused by tunneling affects the safety of adjacent underground structures and aboveground buildings. Therefore, how to evaluate and control the stratum movement is a prominent problem. In this paper, based on the engineering project of an interval tunnel between Shizishan Station and Chuanshi Station in Chengdu Metro Line 7, China, the action mechanism of stratum movement induced by shield tunneling is analyzed, and the effect factors are divided into two categories: ground loss factors and mechanical factors. Combining the advantages of Loganathan method and mirror source-sink method, a new solution of three-dimensional displacement induced by ground loss is proposed. Based on the elastic half-space Mindlin model, the displacement at any point induced by four mechanical effect factors is deduced. Finally, the total displacement is verified by field monitoring data and quantitative analyzed in various parts.
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