Diethylchloronium ((C2H5)2Cl+) has been formed in a high pressure (2-4 Tori-) ion source using a C2H5Cl/CH4 mixture.(C2H5)2CI+ reacts with CzH5Cl (E, = 22 + 2 kcal mol-') at temperatures above 500 K to give t-C4HL The reaction of (C2H5)2Cl+ with B (B = benzene, toluene, isopropylbenzene, mesitylene) yields mainly C2H5B+ at temperatures below 500 K but BH+ is also formed at higher temperatures. The further reactions of C2H5B+ include proton transfer to B yielding BH+ (mesitylene), hydride transfer from B (isopropylbenzene), and reaction with C2H5CI yielding ( C 2 H &~+ (toluene and benzene) and (C2H5),~+ (benzene). The rate constants for the reaction (C2H5)2CI+ + B + C2H5B+ + C2H5CI increase in the order of increasing reaction exothermicity (mesitylene > isopropylbenzene > toluene > benzene). Mesitylene has a negative temperature coefficient, isopropylbenzene has no temperature coefficient, and toluene and benzene show positive temperature coefficients of reaction rate constants consistent with the double well potential theory for gas phase SN2 reactions. isopropylbenztne > tolukne > benztne). Pour ce qui est des coefficients de temperature des constantes des vitesses de reaction, celui du mCsitylkne. est ntgatif alors que l'isopropylbenzkne n'en a pas et que ceux du toldne et du benzkne sont positifs; ces rtsultats sont en accord avec la thCorie du potentiel A double puits pour les reactions SN2 en phase gazeuse.[Traduit par la revue]
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