This research evaluated the feasibility of using vetiver plantlets (Vetiveria zizanioides (L.) Nash) on a floating platform with aeration to degrade phenol (500 mg/L) in illegally dumped industrial wastewater (IDIWW). The IDIWW sample was from the most infamous illegal dumping site at Nong Nae subdistrict, Phanom Sarakham district, Chachoengsao province, Thailand. Laboratory results suggested that phenol degradation by vetiver involves two phases: Phase I, phytopolymerization and phyto-oxidation assisted by root-produced peroxide (HO) and peroxidase (POD), followed by phase II, a combination of phase I with enhanced rhizomicrobial degradation. The first 360-400 h of phenol degradation were dominated by phytopolymerization and phyto-oxidation yielding particulate polyphenols (PPP) or particulate organic matter (POM) as by-products, while phenol decreased to around 145 mg/L. In Phase II, synergistically, rhizomicrobial growth was ∼100-folds greater on the roots of the vetiver plantlets than in the IDIWW and participated in the microbial degradation of phenol at this lower phenol concentration, increasing the phenol degradation rate by more than three folds. This combination of phytochemical and rhizomicrobiological processes eliminated phenol in IDIWW in less than 766 h (32 days), while without the vetiver plantlets, phenol degradation by aerated microbial degradation alone may require 235 days. To our knowledge, this is the first that systematically reveals the complete phenol degradation mechanism by vetiver plantlets in real aerated wastewater.
The application of asphalt hot mix recycling is one challenge in sustainable road pavement research. In addition to the vast amount of research on the performance of recycled asphalt–concrete, the research on the frictional resistance of recycled hot mix asphalt is still limited. The effects of aged asphalt and aged aggregates on the skid resistance of recycled hot mix asphalt were investigated in this research. The aged asphalt and aged aggregates were carefully extracted from the field-reclaimed asphalt pavement, and the engineering and mechanical properties of aged and virgin aggregates were measured. The degradation of recycled hot mix asphalt was simulated using an accelerated polishing machine to mimic road surface abrasion. Accordingly, the initial and final skid resistances of the recycled hot mix asphalt were determined and correlated with the properties of the aged asphalt and aggregates. The initial skid resistance of recycled hot mix asphalt decreased with reductions in penetration and ductility of the blended asphalt. However, the changes in the blended asphalt properties contributed only small variations to the final skid resistances of the recycled hot mix asphalt. The gradations of recycled hot mix asphalt correlated only with the final skid resistances. The aggregate gradations controlled the characteristics of the final skid resistance since the covered binder was partially polished off from the road surface at this stage.
High demand for using parts of natural materials, e.g., cores, fibers or leaves, as alternative additives are being increased. The main reasons are that natural materials can be served as renewable and eco-friendly choices such a sustainable development. Nevertheless, some limitations of applying those natural products, such as biodegradation, UV degradation, or weak bonding, are raised and need to be modified before further handling. One of the modification techniques for bio-based materials is chemical treatment by using alkaline solution (alkalization). Treatment process allows the plant's fiber to have fewer impurities as well as to increase the bonding on its contacting surface area. This research focuses on (i) effects of NaOH solution concentration on the pre-treatment properties of hemp fibers and (ii) self-treatment behavior of hemp fiber in geopolymer composites. The results show that the concentration of NaOH solution directly affected the pre-treatment process of hemp fiber as higher concentration from 1, 3, 5, 8, 10 to 12 Molar provided more vanishing level of fiber impurities, indicated by Contact Angle (CA) measurement and Fourier Transform Infrared (FT-IR) Spectroscopy analysis. With the concept of alkaline treatment, the self-treatment process was therefore applied for hemp fiber incorporated in alkaline-activated geopolymer matrix. The results illustrate the self-treatment behavior of hemp fiber in geopolymer composites, which could improve the final performances of the hardened products without conventional pre-treatment process.
Manuscript Revision (R3) Journal of Construction and Building Materials November 2012 (for publication) characteristics, unsuitable aggregate gradation, ineffective compaction methods, and unreliable performance tests. The project should lead to an improved HMA mix design and result in a costeffective and highly reliable design. To achieve the main aims, the research-specific aims are to: Characterise commonly-used asphalt binders in Thailand with respect to the Performance Grade (PG-grade) system of the SUPERPAVE mix design. Construct a pavement temperature map of North Thailand (termed "the study area") for asphalt binder selection.
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