The recent interest of electronic skin (e‐skin) has pushed the research toward the development of flexible sensors, namely, for pressure detection. Several mechanisms can be used to transduce pressure into electrical signals, but piezoresistivity presents advantages due to its simplicity. The microstructuration of the films composing these sensors is a common strategy to improve their sensitivity. As an alternative to conventional and expensive photolithography techniques and low customizable techniques based on natural molds, a novel strategy for the microstructuration of polydimethylsiloxane (PDMS) films is proposed, based on molds fabricated by laser engraving. After design optimization of these microstructured films, which relies on microcones, piezoresistive sensors with a limit of detection of 15 Pa and a sensitivity of −2.5 kPa−1 in the low‐pressure regime are obtained. These sensors are used with success on the detection of the blood pressure wave at the wrist, thus exhibiting a great potential for health applications.
Indium tin oxide (ITO) is the current standard state‐of‐the‐art transparent conductive oxide (TCO), given its remarkable optical and electrical properties. However, the scarcity of indium carries an important drawback for the long‐term application due to its intensive use in many optoelectronic devices such as displays, solar cells, and interactive systems. Zinc oxide‐based TCOs can be a cost‐effective and viable alternative, but the limitations imposed by their transmittance versus resistivity tradeoff still keep them behind ITO. In this work, an in‐depth study of the structural and compositional material changes induced by specific postannealing treatments is presented, based on aluminum zinc oxide (AZO) and hydrogenated AZO (AZO:H) thin films grown by rf‐magnetron sputtering at room temperature that allows an extensive understanding of the films' electrical/structural changes and the ability to tune their physical parameters to yield increasingly better performances, which put them in line with the best ITO quality standards. The present investigation comprises results of thermal annealing at atmospheric pressure, vacuum, forming gas, H2 and Ar atmospheres and plasmas. Overall the study being performed leads to a decrease in resistivity above 40%, reaching ρ ≈ 3 × 10−4 Ω cm, with an average optical transmittance in the visible region around 88%. Such results are equivalent to the properties of state‐of‐the‐art ITO.
Electronic skin (e-skin) is pursued as a key component in robotics and prosthesis to confer them sensing properties that mimic human skin. For pressure monitoring, a great emphasis on piezoresistive sensors was registered due to the simplicity of sensor design and readout mechanism. For higher sensitivity, films composing these sensors may be micro-structured, usually by expensive photolithography techniques or low-cost and low-customizable molds. Sensors commonly present different sensitivities in different pressure ranges, which should be avoided in robotics and prosthesis applications. The combination of pressure sensing and temperature is also relevant for the field and has room for improvement. This work proposes an alternative approach for film micro-structuration based on the production of highly customizable and low-cost molds through laser engraving. These bimodal e-skin piezoresistive and temperature sensors could achieve a stable sensitivity of −6.4 × 10−3 kPa−1 from 1.6 kPa to 100 kPa, with a very robust and reproducible performance over 27,500 cycles of objects grasping and releasing and an exceptionally high temperature coefficient of resistance (TCR) of 8.3%/°C. These results point toward the versatility and high benefit/cost ratio of the laser engraving technique to produce sensors with a suitable performance for robotics and functional prosthesis.
A short passive planar micromixer was experimentally optimised using statistical methods to determine parameter significance and most desirable geometry.
212941365 ** The first two authors contributed equally to this work.The post-deposition modification of ZnO-based transparent conductive oxides (TCOs) can be the key to produce thin films with optoelectronic properties similar to indium tin oxide (ITO), but at a much lower cost. Here, we present electrooptical results achieved for post-deposition annealing of Al-Zn-O (AZO), AZO:H, Ga-Zn-O:H (GZO:H), and Zn-O:H (ZNO:H) thin films deposited by RF sputtering at room temperature. These studies comprise results of thermal annealing at atmospheric pressure, vacuum, forming gas, H 2 and Ar atmospheres, and H 2 and Ar plasmas, which lead to significant enhancement of their electro-optical properties, which are correlated to morphological and structural improvements. The post-deposition annealing leads to an enhancement in resistivity above 40% for AZO, AZO:H, and GZO:H, reaching r % 2.6-3.5 Â 10 À4 Vcm, while ZnO:H showed a lower improvement of 13%. The averaged optical transmittance in the visible region is about 89% for the investigated TCOs. Such results match the properties of state-of-art ITO (r % 10 À4 Vcm and transmittance in VIS range of 90%) employing much more earth-abundant materials.
Many diseases have their treatment options narrowed and end up being fatal if detected during later stages. As a consequence, point-of-care devices have an increasing importance for routine screening applications in the health sector due to their portability, fast analyses and decreased cost. For that purpose, a multifunctional chip was developed and tested using gold nanoprobes to perform RNA optical detection inside a microfluidic chip without the need of molecular amplification steps. As a proof-of-concept, this device was used for the rapid detection of chronic myeloid leukemia, a hemato-oncological disease that would benefit from early stage diagnostics and screening tests. The chip passively mixed target RNA from samples, gold nanoprobes and saline solution to infer a result from their final colorimetric properties. An optical fiber network was used to evaluate its transmitted spectra inside the chip. Trials provided accurate output results within 3 min, yielding signal-to-noise ratios up to 9 dB. When compared to actual state-of-art screening techniques of chronic myeloid leukemia, these results were, at microscale, at least 10 times faster than the reported detection methods for chronic myeloid leukemia. Concerning point-of-care applications, this work paves the way for other new and more complex versions of optical based genosensors.
Self-assembled microsphere lasers oscillating simultaneously at more than one wavelength in the visible are reported. The lasers consist of micron-scale supraparticles made of CdSxSe1-x/ ZnS quantum dots that emit between 585-605 nm and 625-655 nm.
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