Complexes [Pd3X(PPh,),(PR,),] [BF,] (X = C1, Br, or SCF,; R = Ph or Et), which are the first examples of trinuclear palladium clusters in an oxidation state other than zero, have been synthesised and characterised by 31P n.m.r. spectroscopy and, in the case of (X = C1, R = Et) (I), by X-ray diffraction.
Die Komplexe (I) und (II) reagieren zu ‐dem ersten bekannten gemischten Pt/Pd‐Cluster (IIIa), der mit Z=2 in der RG P1 kristallisiert und als Verunreinigung den Pd‐Cluster (IIIb) enthält, der mit Z=4 in der RG P21/c kristallisiert.
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