The development of large-scale production methods of two-dimensional (2D) crystals, with on-demand control of the area and thickness, is mandatory to fulfill the potential applications of such materials for photovoltaics. Inverted bulk heterojunction (BHJ) organic solar cell (OSC), which exploits a polymer-fullerene binary blend as the active material, is one potentially important application area for 2D crystals. A large ongoing effort is indeed currently devoted to the introduction of 2D crystals in the binary blend to improve the charge transport properties. While it is expected that the nanoscale domains size of the different components of the blend will significantly impact the performance of the OSC, to date, there is no evidence of quantitative information on the interplay between 2D crystals and fullerene domains size. Here, we demonstrate that by matching the size of WSe few-layer 2D crystals, produced by liquid-phase exfoliation, with that of the PCBM fullerene domain in BHJ OSCs, we obtain power conversion efficiencies (PCEs) of ∼9.3%, reaching a 15% improvement with respect to standard binary devices (PCE = 8.10%), i.e., without the addition of WSe flakes. This is the highest ever reported PCE for 2D material-based OSCs, obtained thanks to the enhanced exciton generation and exciton dissociation at the WSe-fullerene interface and also electron extraction to the back metal contact as a consequence of a balanced charge carriers mobility. These results push forward the implementation of transition-metal dichalcogenides to boost the performance of BHJ OSCs.

A novel top-down and universal optical technique for the effective decoration of two-dimensional (2D) nanosheets (NS), graphene oxide (GO), boron nitride (BN) and tungsten disulfide (WS2), with noble metallic nanoparticles (NPs) is reported.

Since the isolation of free standing graphene in 2004, graphene research has experienced a phenomenal growth.