After a 5-minute inspection of 7 objects laid out on a shelf, subjects were seated with the objects behind them and answered questions about the locations and orientations of objects by throwing a switch left or right. The "visual image" subjects were told to imagine that the objects were still in front of them and to respond accordingly. The "real space" (RS) subjects were told to respond in terms of the positions of the objects in real space behind them. Thus correct responses (left vs. right) were completely opposite for the 2 groups. A control group responded while facing a curtain concealing the objects. The task was harder, by time and error criteria, for group RS than for the other 2 groups, but not dramatically so. All RS subjects denied using a response-reversal strategy. Some reported translating the objects from back to front and thus responding as to a mirror-image of the array. When this evasion was discouraged, RS subjects typically reported responding in terms of visual images located behind them and viewed as if by "eyes in the back of the head." The paradox of a visual image that corresponds to no possible visual input is discussed.
Interfacial bonding between fibre and matrix is most critical to obtain enhanced mechanical properties of the resulting composites. Here we present a new surface tailoring method of selective wet etching and organosilicon monomers (3-(Trimethoxysilyl) propyl methacrylate, TMSPMA) deposition process on the short S-Glass fibre as a reinforcing material, resulting in increased mechanical retention and strong chemical bonding between glass fibres and polymer resin (a mixture of triethylene glycol dimethacrylate (TEGDMA) and urethane dimethacrylate (UDMA) monomers). The effect of surface modification on fibre matrix interfacial strength was investigated through microdroplet tests. An S-Glass fibre treated with piranha solution (a mixture of H
2
O
2
and H
2
SO
4
) for 24 hours followed by TMSPMA surface silanization shows highest increase up to 39.6% in interfacial shear strength (IFSS), and critical fibre length could be reduced from 916.0 µm to 432.5 µm. We find the optimal surface treatment condition in that the flexural strength of dental composites reinforced by the S-Glass fibres enhanced up to 22.3% compared to the composites without fibre surface treatments. The significant elevation in strength is attributed to changes in the surface roughness of glass fibres at atomic scale, specifically by providing the multiplied spots of the chemical bridge and nano-mechanical interlocking. The findings offer a new strategy for advanced tailoring of short S-Glass fibres to maximise the mechanical properties of biomedical and dental composites.
Groves * a 1/f noise spectroscopy is used to investigate charge conduction networks within polymer blend spacecharge-limited diodes (SCLDs) fabricated from regioregular poly(3-hexylthiophene) (P3HT) and either isotactic-polystyrene (i-PS) or amorphous-polystyrene (a-PS). Conducting AFM measurements showed that i-PS blends have heterogeneous conduction characterised by current 'hotspots', whereas a-PS blends showed homogeneous conduction. The difference in conducting networks between blends was clearly revealed when examining the noise spectra for the range of blend devices. Furthermore, the shape of the noise spectra suggested that as the blend composition changed, the charges sampled differing breadths of the density of states. These data suggest that noise measurements can be used as an informative technique to electrically characterise the effects of blend morphology and its effects within polymer electronic devices.
The
influence of interfacial shear strength (IFSS) between processed short
S-glass fibers (250 and 350 μm in length, 5 μm in diameter)
and the dental resin (a mixture of urethane dimethacrylate and triethylene
glycol dimethacrylate monomers) on the mechanical properties has been
studied experimentally. The surface profile of short S-glass fibers
was modified using a selective atomic level metal etching process
and simple silanization process to enhance the interfacial properties.
The S-glass fibers were etched in acid solutions to increase the surface
roughness and selectively remove Al3+ and Mg2+ ions, which promoted the mechanical and chemical interfacial bonding
reactions. The single glass fiber tensile and microdroplet pull-out
tests were performed to investigate the effects of interfacial properties
on the flexural strength of the resultant composites. The surface
modified S-glass fibers showed an increase of 11–40% in IFSS
compared to untreated glass fibers. Composites reinforced with 350
μm length glass fibers (AR-70), which were treated in piranha
solution for 4 h, showed the highest improvement in overall mechanical
properties, flexural strength (34.2%), modulus (9.7%), and breaking
energy (51.9%), compared to the untreated fiber-reinforced composites.
The modified Lewis–Nielsen equation was developed using the
effective fiber length factor to accurately predict the modulus of
the short fiber-reinforced composites and validated with experimental
results.
Traditional polymerisation shrinkage (PS) measurement systems measure average PS of dental composites, but the true local PS varies along the length and breadth of the composite. The PS depends on the curing light intensity distribution, resultant degree of conversion (DOC) and the curing rate. In this paper, optical fibre Bragg grating (FBG) sensing based technology is used to measure the linear post-gel PS at multiple locations within dental composite specimens, and is correlated with DOC and curing rate. A commercial dental composite is used, and its post-gel PS and DOC are mapped using embedded fibre Bragg grating sensors at different curing conditions. The distance between the curing lamp and the composite specimen is varied which resulted in different intensity distribution across the specimen. The effect of curing light intensity distribution on PS, curing rate and DOC are investigated for demonstrating a relationship among them. It is demonstrated that FBG sensing method is an effective method to accurately profiling post-gel PS across the specimen.
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