PREVIOUS treatments1*2 of 41" + 2E equilibria in d7 systems have invoked electron delocalisation via w-bonding in order to explain the observation of "crossover" behaviour at values of A, the ligand-field splitting parameter, which are very much less than v, the mean electron-pairing energy.
Durch Reaktion der dreizähnigen Liganden mit Co‐perchlorat in Tiiäthylorthoformiat werden die Komplexe (Ia) und bei Zugabe von H2O, die Co(III)‐Komplexe (Ib)dar‐ ′ des bereits bekannten gestellt.
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