Paul C. Blake scite author profile

Reduction of [UCp'f2X2] [Cp" = r ~-C ~H ~( s i M e ~) ~; X = CI, Br, o r I] or [ { U C P " ~( ~~-B F ~) ( ~~-F ) } ~]with Na/Hg in toluene yields the lipophilic (and n.m.r. characterisable) compounds [{UCp"2X},] (X = F, CI, Br, or I), which are versatile precursors to uranocene (111 or IV) compounds; X-ray data on the chloro-and bromo-derivatives reveal them to be the first uranocene(iit) halide dimers (i.e., n = 2, with p X -) .

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Synthesis, spectroscopic properties and crystal structures of [ML₂Cl₂][M = Th or U; L =η-C₅H₃(SiMe₃)₂-1,3] and [UL₂X₂](X = Br, I or BH₄)

Blake¹,

Läppert²,

Taylor³

et al. 1995

J. Chem. Soc., Dalton Trans.

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Some aspects of the coordination and organometallic chemistry of thorium and uranium (MIII, MIV, UV) in +3 and +4 oxidation states

Blake

Läppert²,

Taylor³

et al. 1987

Inorganica Chimica Acta

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Paul C. Blake

The synthesis and characterisation, including X-ray diffraction study, of [Th{η-C₅H₃(SiMe₃)₂}₃]; the first thorium(III) crystal structure

Synthesis, properties and structures of the tris(cyclopentadienyl)thorium(III) complexes [Th{η5-C5H3(SiMe2R)2-1,3}3] (R=Me or tBu)

A complete series of uranocene(III) halides [{UCp″₂X}_n][X = F, Cl, Br, or I; Cp″=η-C₅H₃(SiMe₃)₂]; single-crystal X-ray structure determinations of the chloride and bromide (n= 2 for X^–=µ-Cl^–or µ-Br^–)

Synthesis, spectroscopic properties and crystal structures of [ML₂Cl₂][M = Th or U; L =η-C₅H₃(SiMe₃)₂-1,3] and [UL₂X₂](X = Br, I or BH₄)

Some aspects of the coordination and organometallic chemistry of thorium and uranium (MIII, MIV, UV) in +3 and +4 oxidation states

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Paul C. Blake

The synthesis and characterisation, including X-ray diffraction study, of [Th{η-C5H3(SiMe3)2}3]; the first thorium(III) crystal structure

Synthesis, properties and structures of the tris(cyclopentadienyl)thorium(III) complexes [Th{η5-C5H3(SiMe2R)2-1,3}3] (R=Me or tBu)

A complete series of uranocene(III) halides [{UCp″2X}n][X = F, Cl, Br, or I; Cp″=η-C5H3(SiMe3)2]; single-crystal X-ray structure determinations of the chloride and bromide (n= 2 for X–=µ-Cl–or µ-Br–)

Synthesis, spectroscopic properties and crystal structures of [ML2Cl2][M = Th or U; L =η-C5H3(SiMe3)2-1,3] and [UL2X2](X = Br, I or BH4)

Some aspects of the coordination and organometallic chemistry of thorium and uranium (MIII, MIV, UV) in +3 and +4 oxidation states

Contact Info

Product

Resources

About

The synthesis and characterisation, including X-ray diffraction study, of [Th{η-C₅H₃(SiMe₃)₂}₃]; the first thorium(III) crystal structure

A complete series of uranocene(III) halides [{UCp″₂X}_n][X = F, Cl, Br, or I; Cp″=η-C₅H₃(SiMe₃)₂]; single-crystal X-ray structure determinations of the chloride and bromide (n= 2 for X^–=µ-Cl^–or µ-Br^–)

Synthesis, spectroscopic properties and crystal structures of [ML₂Cl₂][M = Th or U; L =η-C₅H₃(SiMe₃)₂-1,3] and [UL₂X₂](X = Br, I or BH₄)