Crystal Structure and Electronic Properties of Ammine[tris(2-aminoethyl)amine]copper(i~) Diperchlorate and Potassium Penta-amminecopper( 11) Tris( hexaf luorophosphate)By M a r y Duggan, Noel Ray, Brian Hathaway,' and (in part)
The vacuum ultraviolet laser-excited photoion-pair formation spectrum of CH 3Br has been measured under high resolution in the threshold region. The (2 + 1) and (3 + 1) resonance-enhanced multiphoton ionization spectra in the same energy region are also reported. By comparison of the spectra in this and a more extended region, resonances in the photoion-pair formation spectrum are assigned to p and f Rydberg states. It is concluded that all the structure in the photoion-pair formation spectrum near threshold can be accounted for by members of the Omega = 0 subset of Rydberg states that act as doorway states to the ion channel.
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