This study presents a theoretical and practical evaluation of zinc evaporation from bottom zinc dross (hard zinc) as a secondary zinc source (zinc content approximately 94–97%), which originates in the batch hot-dip galvanizing process. The thermodynamics of the zinc evaporation process were studied under the normal pressure (100 kPa) in the inert atmosphere, using argon with flow rate 90 mL/min. Samples were subjected to the evaporation process for 5, 10 and 20 min under the temperature of 700 °C and 800 °C, respectively. For the theoretical thermodynamic study, HSC Chemistry 6.1 software was used and final products, as well as residuals after the evaporation process, were analyzed by SEM (Scanning Electron Microscopy) and EDX (Energy Dispersive X-ray). Calculated and experimental argon consumption in the process of zinc evaporation has been compared. A high purity zinc with efficiency over 99% was reached. Due to a dynamic regime, argon consumption at the temperature of 700 °C and 800 °C were 7 times and 3 times, respectively, less than calculated.
Superalloys are a group of alloys developed for use during long-term heat exposure above 650 °C. Properties and applications of superalloys are described in the present work. The work includes statistics about superalloys demand, market value and the current price. Division of superalloys according to basic element is mentioned. Nickel-based superalloys are further divided into two groups according to their use. Afterwards, the paper is focused mainly on nickel-based superalloys. Examples of nickel-based superalloys are listed in the work. Recycling possibilities of nickel-based superalloys are stated and analysed. General scheme of processing nickel-based superalloy scrap with regard to the content of rhenium is proposed and shortly discussed. The best-known companies dealing with superalloy scrap recycling are mentioned further.
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