Here we report the bias-evolution of the electrical double layer structure of an ionic liquid on highly ordered pyrolytic graphite measured by atomic force microscopy. We observe reconfiguration under applied bias and the orientational transitions in the Stern layer. The synergy between molecular dynamics simulation and experiment provides a comprehensive picture of structural phenomena and long and short-range interactions, which improves our understanding of the mechanism of charge storage on a molecular level.
Five different ionic liquids containing the tetracyanoborate anion were synthesized and evaluated for CO 2 separation performance. Measured CO 2 solubility values were exceptionally high compared to analogous ionic liquids with different anions and ranged from 0.128 mol·L -1 ·atm -1 to 0.148 mol·L -1 ·atm -1 . In addition, CO 2 permeability and CO 2 /N 2 selectivity values were measured using a supported ionic liquid membrane architecture and the separations performance of the ionic liquid membranes exceeded the 10 Robeson upper bound. These results establish the distinct potential of ionic liquids with the tetracyanoborate, [B(CN) 4 ], anion for the separation of CO 2 . 75 sensitized solar cells. 12,13 Recently, however, we reported a high CO 2 solubility and CO 2 /N 2 selectivity in an imidazoliumbased ionic liquid with a [B(CN) 4 ] anion. 14 Since this first report of the high CO 2 solubility, permeability and CO 2 /N 2 selectivity of the [B(CN) 4 ] anion, interest in this 80 RTIL for gas separations has grown; quantum mechanical Fax: 865-576-5235; Tel:865-576-7307 † Electronic Supplementary Information (ESI) available: Temperature dependent viscosity values, detailed description of synthesis and NMR 25 results are included. See
Molecular dynamics (MD) simulations of 1-alkyl-1-methylpyrrolidinium
bis(trifluoromethanesulfonyl)imide ([C
n
MPy][Tf2N], n = 3, 4, 6, 8, 10) were
conducted using an all-atom model. Radial distribution functions (RDF)
were computed and structure functions were generated to compare with
new X-ray scattering experimental results, reported herein. The scattering
peaks in the structure functions generally shift to lower Q values with increased temperature for all the liquids
in this series. However, the first sharp diffraction peak (FSDP) in
the longer alkyl chain liquids displays a marked shift to higher Q values with increasing temperature. Alkyl chain-dependent
ordering of the polar groups and increased tail aggregation with increasing
alkyl chain length were observed in the partial pair correlation functions
and the structure functions. The reasons for the observed alkyl chain-dependent
phenomena and temperature effects were explored.
In this work, we provide new experimental evidence for chain length-dependent self-aggregation in room temperature ionic liquids (RTILs) using fluorescence correlation spectroscopy (FCS). In studying a homologous series of N-alkyl-N-methylpyrrolidinium bis(trifluoromethylsulfonyl) imide, [C(n)MPy][Tf(2)N] RTILs of varying alkyl chain length (n = 3, 4, 6, 8, and 10), biphasic rhodamine 6G solute diffusion dynamics were observed; both the fast and slow diffusion coefficients decreased with increasing alkyl chain length, with the relative contribution from slower diffusion increasing for longer-chain [C(n)MPy][Tf(2)N]. We propose that the biphasic diffusion dynamics originate from self-aggregation of the nonpolar alkyl chains in the cationic [C(n)MPy](+).
NMR spectroscopy and time-resolved fluorescence anisotropy decay (TRFAD) are two of the most commonly used methods to study solute-solvent interactions. However, only a few studies have been reported to date using a combined NMR and TRFAD approach to systematically investigate the overall picture of diffusional and rotational dynamics of both the solute and solvent. In this paper, we combined NMR and TRFAD to probe fluorescent rhodamine dye in a pyrrolidinium-based room temperature ionic liquid (RTIL), an emergent environmentally friendly solvent type used in several energy-related applications. A specific interaction of the R6G cation and [Tf2N] anion was identified, resulting in near-stick boundary condition rotation of R6G in this RTIL. The diffusional rates of the R6G solute and [C4mpyr][Tf2N] solvent derived from (1)H NMR suggest the rates are proportional to their corresponding hydrodynamic radii. The (1)H and (13)C NMR studies of self-rotational dynamics of [C4mpyr][Tf2N] showed that the self-rotational correlation time of [C4mpyr](+) is 47 ± 2 ps at 300 K. At the same temperature, we find that the correlation time for N-CH3 rotation in [C4mpyr](+) is 77 ± 2 ps, comparable to overall molecular reorientation. This slow motion is attributed to properties of the cation structure.
The search for a better carbon dioxide (CO(2) ) capture material is attracting significant attention because of an increase in anthropogenic emissions. Porous materials are considered to be among the most promising candidates. A series of porous, nitrogen-doped carbons for CO(2) capture have been developed by using high-yield carbonization reactions from task-specific ionic liquid (TSIL) precursors. Owing to strong interactions between the CO(2) molecules and nitrogen-containing basic sites within the carbon framework, the porous nitrogen-doped compound derived from the carbonization of a TSIL at 500 °C, CN500, exhibits an exceptional CO(2) absorption capacity of 193 mg of CO(2) per g sorbent (4.39 mmol g(-1) at 0 °C and 1 bar), which demonstrates a significantly higher capacity than previously reported adsorbents. The application of TSILs as precursors for porous materials provides a new avenue for the development of improved materials for carbon capture.
The expansion of porous carbon electrodes in a room temperature ionic liquid (RTIL) is studied using in situ atomic force microscopy (AFM). The effect of carbon surface area and pore size/pore size distribution on the observed strain profile and ion kinetics is examined. Additionally, the influence of the potential scan rate on the strain response is investigated. By analyzing the strain data at various potential scan rates, information on ion kinetics in the different carbon materials is obtained. Molecular dynamics (MD) simulations are performed to compare with and provide molecular insights into the experimental results; this is the first MD work investigating the pressure exerted on porous electrodes under applied potential in a RTIL electrolyte. Using MD, the pressure exerted on the pore wall is calculated as a function of potential/charge for both a micropore (1.2 nm) and a mesopore (7.0 nm). The shape of the calculated pressure profile matches closely with the strain profiles observed experimentally.
An equimolar mixture of 1-methyl-1-propylpyrrolidinium bis(trifluoromethylsulfonyl)imide ([C3mpy][Tf2N]), 1-methyl-1-butylpiperidinium bis(trifluoromethylsulfonyl)imide ([C4mpip][Tf2N]) was investigated by classic molecular dynamics (MD) simulation. Differential scanning calorimetry (DSC) measurements verified that the binary mixture exhibited lower glass transition temperature than either of the pure room-temperature ionic liquids (RTILs). Moreover, the binary mixture gave rise to higher conductivity than the neat RTILs at lower temperature range. In order to study its capacitive performance in supercapacitors, simulations were performed of the mixture, and the neat RTILs used as electrolytes near an onion-like carbon (OLC) electrode at varying temperatures. The differential capacitance exhibited independence of the electrical potential applied for three electrolytes, which is in agreement with previous work on OLC electrodes in a different RTILs. Positive temperature dependence of the differential capacitance was observed, and it was dominated by the electrical double layer (EDL) thickness, which is for the first time substantiated in MD simulation.
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