Migration of stray methane gas near the town of Dimock, Pennsylvania, has been at the center of the debate on the safety of shale gas drilling and hydraulic fracturing in the United States. The presented study relates temporal variations in molecular concentrations and stable isotope compositions of methane and ethane to shale-gas well activity (i.e., vertical/horizontal drilling, hydraulic fracturing and remedial actions). This was accomplished by analyzing data collected, between 2008 and 2012, by state and federal agencies and the gas well operator. In some cases, methane migration started prior to hydraulic fracturing. Methane levels of contaminated water wells sampled were one to several orders of magnitude greater than the concentrations due to natural variation in water wells of the local area. Isotope analyses indicate that all samples had a thermogenic origin at varying maturity levels, but from formations above the hydraulically fractured Marcellus Shale. The results from the initial water well samples were similar to annular gas values, but not those of production gases. This indicates that leakage by casing cement seals most likely caused the impacts, not breaks in the production casing walls. Remediation by squeeze cementing was partially effective in mitigating impacts of gas migration. In several cases where remediation caused a substantial reduction in methane levels, there were also substantial changes in the isotope values, providing evidence of two sources, one natural and the other man-induced. Sampling water wells while venting gas wells appears to be a cost-effective method for determining if methane migration has occurred.

More than 1 million wells may have been completed using hydraulic fracturing techniques in the USA alone; however, there have been few case studies exploring the impacts on water resources due to methane migration. This study evaluated the results of three investigations initiated by the US Environmental Protection Agency, that were subsequently described in published studies at Dimock in Pennsylvania, Parker-Hood County in Texas, and Pavillion in Wyoming, as well as another study completed at Sugar Run in northeast Pennsylvania. In addition, earlier investigations at Shaws Corner in Pennsylvania, Jackson County in West Virginia, Garfield County in Colorado, and Bainbridge in Ohio are summarized. The most common cause of incidents was the presence of uncemented sections of production casings in wells that allowed gas migration from intermediate depths to shallow freshwater aquifers. In three cases, an inadequate depth of the primary top of cement (TOC) also contributed to impacts. Sources of methane were best identified through analyses of isotopes on samples from production casings, annular spaces, and water wells. In Dimock, some isotope signatures changed with time, after the completion of remedial actions. In Parker-Hood County, where impacts were not related to gas well activity, noble gas analyses were also needed to determine the source of gas. At Pavillion, where maximum methane concentrations in water wells were <1 mg/L, no significant impacts were documented. For all the sites, most or all of the fugitive gas incidents may have been prevented by fully cementing production casings to the land surface.

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Most studies of fractured-rock aquifers are about analytical models used for evaluating aquifer tests or numerical methods for describing groundwater flow, but there have been few investigations on how to estimate the reliable long-term drought yields of individual hard-rock wells. During the drought period of 1998 to 2002, many municipal water suppliers in the Piedmont/Blue Ridge areas of central Maryland (USA) had to institute water restrictions due to declining well yields. Previous estimates of the yields of those wells were commonly based on extrapolating drawdowns, measured during short-term singlewell hydraulic pumping tests, to the first primary water-bearing fracture in a well. The extrapolations were often made from pseudo-equilibrium phases, frequently resulting in substantially over-estimated well yields. The methods developed in the present study to predict yields consist of extrapolating drawdown data from infinite acting radial flow periods or by fitting type curves of other conceptual models to the data, using diagnostic plots, inverse analysis and derivative analysis. Available drawdowns were determined by the positions of transition zones in crystalline rocks or thin-bedded consolidated sandstone/limestone layers (reservoir rocks). Aquifer dewatering effects were detected by type-curve matching of step-test data or by breaks in the drawdown curves constructed from hydraulic tests. Operational data were then used to confirm the predicted yields and compared to regional groundwater levels to determine seasonal variations in well yields. Such well yield estimates are needed by hydrogeologists and water engineers for the engineering design of water systems, but should be verified by the collection of longterm monitoring data.

Aquifer test methods have greatly improved in recent years with the advent of inverse analysis, derivative analysis, and diagnostic plots. Updated analyses of past aquifer tests allow for improved interpretations of the data to enhance the knowledge and the predictive capabilities of the flow system. This work thoroughly reanalyzes a series of pre-and post-hydraulic fracturing, single-well aquifer tests conducted in two crystalline rock wells in New Hampshire as part of an early 1970's study. Previous analyses of the data had relied on older manual type-curve methods for predicting the possible effects of hydraulic fracturing. This work applies inverse analysis, derivative analysis, and diagnostic plots to reanalyze the 1970's aquifer test data. Our results demonstrate that the aquifer tests were affected by changes in flow regimes, dewatering of the aquifer and discrete fractures, and changes due to well development. Increases in transmissivities are related to well development prior to hydraulic fracturing, propagation of a single, vertical fracture hydraulically connecting the two wells after stimulation and expansion of troughs of depression. After hydraulic fracturing, the estimated total yield of the individual wells increased by 2.5 times due to the hydraulic fracturing. However, the wells may be receiving water from the same source, and well interference may affect any significant increase in their combined yield. Our analyses demonstrate the value in applying inverse analysis, derivative analysis, and diagnostic plots over the conventional method of manual type-curve analysis. In addition, our improvement in the aquifer test interpretation of the 1970's test data has implications for more reliable estimates of sustained well yields.