In spite of color being one of the physicochemical parameters most commonly used to characterize ornamental stone, there is yet no standardized protocol for measuring this parameter. Such a protocol is of particular importance for characterizing the color of heterogeneous surfaces, as in the case of granite. The aim of the present study was to determine the minimum area and the number of measurements required to characterize the color of granite rocks. A spectrophotometer and a tristimulus colorimeter, were used to measure the color of granite samples, and the measurements were expressed in CIE L*a*b* color system units. Three parameters were considered as variable factors: the type of rock (Labrador Claro, Grissal, Rosa Porrin˜o, and Blanco Cristal), surface finish (polished, honed, sawn, and flamed), and target area (circular apertures of diameter 5, 8, 10, and 50 mm). The results of the application of multivariate analysis of variance and of the classical CIELAB formula and CIE L*a*b*-based color-difference formulae (i.e., CIE94 and CIEDE2000) to the data revealed that, although all considered factors affected the minimal area and the number of measurements required, the different circular apertures of both the instruments can be disregarded if the number of measurements and area recommended in this study are used.
Nitrocellulose is one of the most commonly used compounds in ammunition and paint industries and its recalcitrance to degradation has a negative impact on human health and the environment. In this study the capability of Desulfovibrio desulfuricans ATCC 13541 to degrade nitrocellulose as binder in paint was assayed for the first time. Nitrocellulose-based paint degradation was followed by monitoring the variation in nitrate, nitrite and ammonium content in the culture medium using ultraviolet-visible spectroscopy. At the same time cell counts and ATP assay were performed to estimate bacterial density and activity in all samples. Infrared spectroscopy and colourimetric measurements of paint samples were performed to assess chemical and colour changes due to the microbial action. Microscope observations of nitrocellulose-based paint samples demonstrated the capability of the bacterium to adhere to the paint surface and change the paint adhesive characteristics. Finally, preliminary studies of nitrocellulose degradation pathway were conducted by assaying nitrate-and nitrite reductases activity in D. desulfuricans grown in presence or in absence of paint. We found that D. desulfuricans ATCC 13541 is able to transform nitrocellulose as paint binder and we hypothesised ammonification as degradation pathway. The results suggest that D. desulfuricans ATCC 13541 is a good candidate as a nitrocellulose-degrading bacterium.
The sol-gel process has been found to be successful in applications for the conservation and restoration of stone. However, a well-known drawback of the materials obtained by this process is their tendency to crack during drying inside the pores of the treated stone. In this article, we present an overview of our current research centred on producing crack-free sol-gel materials for consolidating and protecting building stone. A novel synthesis, in which a surfactant acts as a template to make the pore size of the gel network coarser and more uniform, is shown to provide an effective alternative for preventing the cracking of consolidants. We also highlight an alternative pathway, in which we add an organic component to the silica precursor in the presence of the surfactant. The hybrid organic-inorganic gel prepared in our laboratory provides excellent waterproofing to the stones under study.
Microbial activity has an important impact on the maintenance of cultural heritage materials, owing to the key role of microorganisms in many deterioration processes. In order to minimize such deleterious effects, there is a need to fine-tune methods that detect and characterize microorganisms. Trends in microbiology indicate that this need can be met by incorporating modern techniques. All of the methods considered in this review paper are employed in the identification, surveillance, and control of microorganisms, and they have two points in common: They are currently used in microbial ecology (only literature from 2009 to 2015 is included), and they are often applied in the cultural heritage sector. More than 75 peer-reviewed journal articles addressing three different approaches were considered: molecular, sensory and morphological, and biocontrol methods. The goal of this review is to highlight the usefulness of the traditional as well as the modern methods. The general theme in the literature cited suggests using an integrated approach.
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