The purpose of this research was to fabricate the particle board from the coffee husk. The coffee husk from Chumphon province of Thailand was collected, prepared and separated into four groups such as outer husk, inner husk, the mixture of inner and outer husk and husk from the milling process. The coffee husk particle sheet was formed by the compression molding with the heater. Then the coffee husk particle sheets were the mechanical properties testing. The results showed the coffee husk particle sheet from milling process pass the Thai industrial standard (TIS.876/2547). However, the results of swelling and water absorption indicated that all the coffee husk sheet were not passed the TIS.876/2547. The effect of coffee husk particle size on mechanical properties was clarified. The coffee husk particle sheet from the particle size of 2, 4 and 6 mm was mechanical testing and follow TIS.876/2547. The coffee particle size of 2 mm showed the passing the standard. Moreover, the effect of isocyanate adhesive on mechanical properties was investigated. The weight percentage range of isocyanate adhesive on coffee husk from 7 to 13 %wt was carried out. The weight percentage of 9, 11 and 13 showed according to TIS.876/2547. From the experiment indicated that the coffee husk could be applied to the wood particle board industrial.
The chicken eggshell waste from food processing was synthesized as the hydroxyapatite for fluxing agent replacement in ceramic manufacturing. The main fluxing agents in Thailand ceramic manufacturing are natural potash feldspar (k‐feldspar) and animal bone ash. To overcome the problems of inconstant properties and the lack of k‐feldspar, the hydroxyapatite from chicken eggshell waste was selected as fluxing agent for the enhancement of the ceramic product. In this work, the hydroxyapatite with 0, 5, 10, and 15 wt% was replaced with the k‐feldspar in the ceramic samples. The results revealed the physical and mechanical properties of the ceramic samples with various hydroxyapatite contents were investigated after heat treatment in the temperature range of 1000–1200 °C. The ceramic samples added with hydroxyapatite have higher linear shrinkage and bulk density as compared with the ceramic sample without hydroxyapatite. The apparent porosity and water absorption decreased to near zero after the heat treatment at a temperature of 1200 °C. Moreover, the results showed that the physical properties affected the mechanical properties improvement after the hydroxyapatite addition and heat treatment process.
Chitosan (CS) with excellent biomedical properties was mixed with polyvinyl alcohol (PVA) to be used as the spinning solution. The spinning solutions with various concentrations of CS:PVA from 10:90% to 50:50% (v/v) were investigated. Tween 80 (T80) was added in the spinning solutions of CS and PVA. The nanofiber mats with and without T80 addition obtained from the spinning solutions by electrospinning technique were investigated and addressed. The results showed that the viscosity of the CS and PVA spinning solutions increased with increasing the CS concentration, whereas the viscosity decreased after T80 addition. The nanofiber mats with 10–30% CS concentrations were prepared successfully as a smooth surface and high dense nanofiber mat. The average diameter of the nanofiber decreased with increasing the CS concentration. The increase in the CS concentration of the nanofiber mat can increase the mechanical and antibacterial properties, whereas the wettability and drug release property were decreased. Moreover, the nanofiber mats with T80 addition had higher mechanical property and wettability than the nanofiber mats without T80 addition. Finally, the T80 addition can enhance hydrophilicity and promote the drug release property of the nanofiber mat.
The zinc (Zn) substituted hydroxyapatite were synthesized using a chemical precipitation method. The chemical precursors were prepared from di-ammonium hydrogen orthophosphate, calcium oxide (CaO) derived from chicken eggshell and zinc nitrate (Zn(NO3)2). The Zn(NO3)2contents in the prepared samples were varied from 1 to 25 %wt of CaO. The Zn substituted hydroxyapatite were heated at the various temperatures from 200 to 1300 °C in the furnace with an incremental temperature of 100 °C. The crystal structure, function group and morphology of sample were analyzed by X-ray diffraction (XRD), Fourier transforms infrared spectroscopy (FTIR) and field emission scanning electron microscopy (FESEM), respectively. The results show that the hydroxyapatite doped Zn was a hydroxyapatite phase as well as pure hydroxyapatite. The crystalline size of sample decreased with increasing the Zn content. And, the crystallinity of hydroxyapatite phase was increased following by increasing heat treatment temperature. However, the amount of Zn has the effect on phase transformation of hydroxyapatite phase after heat treatment. Zn concentration accelerates hydroxyapatite transforms to β-tricalcium phosphate phase.
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