The synthesis of aryl/vinyl carboxylic acids from Csp2-bound halides (Cl, Br, I) in a carbonylative path by using silyl formate (from CO2 and hydrosilane) as an instant CO-surrogate.
A Cu(ii)–Ni(ii) catalyzed tandem hydrocarboxylation of terminal alkynes with CO2 and hydrosilane is achieved via a hydro-silyloxycarbonylation process.
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