Understanding the adsorption and growth mechanisms of large π -conjugated molecules on noble metal surfaces is a crucial aspect for designing and optimizing electronic devices based on organic materials. The investigation of adsorption heights for these molecules on different surfaces can be a direct measure for the strength of the adsorbate-substrate interaction, and gives insight into the fundamental bonding mechanisms. However, the adsorption strength is often also influenced by intermolecular (lateral) interactions which cause, e.g., island formation in the submonolayer regime and influence the adsorption geometry of individual molecules. The lateral structure can then dominate the vertical structure formation and influence the adsorbate-substrate interaction. In this context, the adsorption of copper-phthalocyanines on noble metal surfaces [Au(111), Ag(111), and Cu (111)] represents an ideal model system since the lateral structure formation, as well as the molecular adsorption geometries, strongly depend on coverage and temperature, and hence can be tuned easily. We demonstrate that for CuPc/Au(111), a system dominated by physisorption, the adsorption height of the molecules is independent from the lateral adsorption geometry. In contrast, a strong chemisorption of CuPc on Cu(111) shows a clear gradient in the interaction strength: Individual molecules in diluted phases are significantly stronger bonded than molecules in dense phases. This finding quantifies the increase of the exchange correlation in the binding process, which goes along with the tendency to a more site-specific adsorption geometry at small coverages.
In this work, five types of MnO 2 nanostructres (nanowires, nanotubes, nanoparticles, nanorods, and nanoflowers) were synthesized with a fine control over their α-crystallographic form by hydrothermal method. The electrocatalytic activities of these materials were examined toward oxygen reduction reaction (ORR) in alkaline medium. Numerous characterizations were correlated with the observed activity by analyzing their crystal structure (TGA, XRD, TEM), material morphology (FE-SEM), porosity (BET), inherent structural nature (IR, Raman, ESR), surfaces (XPS), and electrochemical properties (Tafel, Koutecky−Levich plots and % of H 2 O 2 produced). Moreover, X-ray absorption near-edge structure (XANES) and the extended X-ray absorption fine structure (EXAFS) analysis were employed to study the structural information on the MnO 2 coordination number as well as interatomic distance. These combined results show that the electrocatalytic activities are significantly dependent on the nanoshapes and follow an order nanowire > nanorod > nanotube > nanoparticle > nanoflower. α-MnO 2 nanowires possess enhanced electrocatalytic activity compared to other shapes, even though the nanotubes possess a much higher BET surface area. In the ORR studies, α-MnO 2 nanowires displayed Tafel slope of 65 mV/decade, n-value of 3.5 and 3.6% of hydrogen peroxide production. The superior ORR activity was attributed to the fact that it possesses active sites composed with two shortened Mn− O bonds along with a Mn−Mn distance of 2.824 Å, which provides an optimum requirement for the adsorbed oxygen in a bridge mode favoring the direct 4 electron reduction. In accordance with the first principles based density functional theory (DFT), the enhancement in ORR activity is due to the less activation energy needed for the reaction by the (211) surface than all other surfaces.
Spin valves have revolutionized the field of magnetic recording and memory devices. Spin valves are generally realized in thin film heterostructures, where two ferromagnetic (FM) layers are separated by a nonmagnetic conducting layer. Here, we demonstrate spin-valve-like magnetoresistance at room temperature in a bulk ferrimagnetic material that exhibits a magnetic shape memory effect. The origin of this unexpected behavior in Mn(2)NiGa has been investigated by neutron diffraction, magnetization, and ab initio theoretical calculations. The refinement of the neutron diffraction pattern shows the presence of antisite disorder where about 13% of the Ga sites are occupied by Mn atoms. On the basis of the magnetic structure obtained from neutron diffraction and theoretical calculations, we establish that these antisite defects cause the formation of FM nanoclusters with parallel alignment of Mn spin moments in a Mn(2)NiGa bulk lattice that has antiparallel Mn spin moments. The direction of the Mn moments in the soft FM cluster reverses with the external magnetic field. This causes a rotation or tilt in the antiparallel Mn moments at the cluster-lattice interface resulting in the observed asymmetry in magnetoresistance.
The adsorption of molecular acceptors
is a viable method for tuning
the work function of metal electrodes. This, in turn, enables adjusting
charge injection barriers between the electrode and organic semiconductors.
Here, we demonstrate the potential of pyrene-tetraone (PyT) and its
derivatives dibromopyrene-tetraone (Br-PyT) and dinitropyrene-tetraone
(NO2-PyT) for modifying the electronic properties of Au(111)
and Ag(111) surfaces. The systems are investigated by complementary
theoretical and experimental approaches, including photoelectron spectroscopy,
the X-ray standing wave technique, and density functional theory simulations.
For some of the investigated interfaces the trends expected for Fermi-level
pinning are observed, i.e., an increase of the metal work function
along with increasing molecular electron affinity and the same work
function for Au and Ag with monolayer acceptor coverage. Substantial
deviations are, however, found for Br-PyT/Ag(111) and NO2-PyT/Ag(111), where in the latter case an adsorption-induced work
function increase of as much as 1.6 eV is observed. This behavior
is explained as arising from a face-on to edge-on reorientation of
molecules in the monolayer. Our calculations show that for an edge-on
orientation much larger work-function changes can be expected despite
the prevalence of Fermi-level pinning. This is primarily ascribed
to a change of the electron affinity of the adsorbate layer that results
from a change of the molecular orientation. This work provides a comprehensive
understanding of how changing the molecular electron affinity as well
as the adsorbate structure impacts the electronic properties of electrodes.
Le Bail and Rietveld analysis of high resolution synchrotron x-ray powder diffraction (SXRPD) data shows unambiguous signatures of the failure of the commensurate 3M modulation model. Using (3 + 1) dimensional superspace group formalism, we have not only confirmed the incommensurate modulation in the premartensite phase with a modulation wavevector of q = 0.337 61(5)c* but also determined the superspace group (Immm(00γ)s00), atomic positions and amplitude of modulations for the incommensurate premartensite phase of Ni2MnGa for the first time. Our results may have important implications in the understanding of the martensitic transition and hence the magnetic field induced strains.
The modulated structure of the martensite phase of Ni 2 MnGa is revisited using high resolution synchrotron x-ray powder diffraction (SXRPD) measurements, which reveals higher order satellite reflections up to the 3 rd order and phason broadening of the satellite peaks. The structure refinement, using the (3+1) dimensional superspace group approach, shows that the modulated structure of Ni 2 MnGa can be described by orthorhombic superspace group 2
Oxygen electrocatalysis is vital for advanced energy technologies, but inordinate challenges remain due to the lack of highly active earth-abundant catalysts.
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