There is an environmental concern regarding the use of petroleum-based
lubricants, which are generally toxic and nonbiodegradable. Biobased
lubricants, such as vegetable oils, are the alternative: they show
excellent lubricity, are readily biodegradable and nontoxic. However,
a major disadvantage of using vegetable oils in lubricant applications
is their lack of thermo-oxidative stability, which can be improved
by antioxidant additives. Here, we propose the use of lignin-based
additives in biolubricant formulations to improve this feature, based
on lignin’s known antioxidant properties. To ensure a stable
dispersion in vegetable oil, lignin was partially esterified. Antioxidant
properties of lignin before and after palmitoylation were demonstrated
in a 2,2-diphenyl-1-picrylhydrazyl (DPPH) assay. Four different lignin-based
fractions, commercial Protobind P1000 soda lignin from straw, solvolytically
fractionated Protobind P1000 lignin and two lignin fractions from
reductively catalyzed fractionation (RCF) of native birch wood, were
tested in biolubricant formulations with castor oil as base oil. Those
lignin fractions exhibited excellent performance compared to butylated
hydroxytoluene (BHT), a commonly used petroleum-based antioxidant.
Formulations of modified lignin in castor oil possess improved thermo-oxidative
stability, as illustrated by their increased oxidation induction time.
Additionally, rheological and tribological tests demonstrate similar,
or in some cases improved, lubricating properties compared to castor
oil. This study showcases the successful incorporation of lignin-based
antioxidants in biolubricant formulations, tackling the major disadvantage
of vegetable oils as environment-friendly lubricants.
A mild thermal solvolysis process using alcohols for the valorization of technical lignin into crude lignin oil (CLO) is presented. The solubilization process results in lower molecular weight lignin fragments...
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