Sargassum muticum, an invasive macroalgae in Europe, was employed as material for third generation bioethanol production. As a first step, autohydrolysis was chosen as an eco-friendly pretreatment, seeking for a high enzymatic susceptibility of the solid phase and high content of hexoses as glucose, galactose and mannose, in both liquid and solid phases, which can be subsequently transformed in ethanol via fermentation. Besides, the search of a minimum consumption of energy in the pretreatment is also a key challenge in bioethanol production. At optimum conditions of autohydrolysis pretreatment, more than 90% of the glucan was recovered in the solid phase (while the other 10% appeared as glucooligosaccharides and glucose in the liquid phase). In the enzymatic hydrolysis carried out with the solid phases, glucan to glucose conversions of 94 and 89% were obtained, with the solid mixed with water and the whole slurry, respectively. Moreover, the whole slurry experiments, where all hexoses present in the raw material (glucose, galactose and mannose) from the solid and the liquid phases are fermented, allows to reach maximum ethanol yields of 80% (14.10 g of ethanol/L) referred to the theoretical yield, in a short time.
Concerns about fossil fuels depletion has led to seek for new sources of energy. The use of marine biomass (seaweed) to produce biofuels presents widely recognized advantages over terrestrial biomasses such as higher production ratio, higher photosynthetic efficiency or carbon-neutral emissions. In here, interesting seaweed sources as a whole or as a residue from seaweed processing industries for biofuel production were identified and their diverse composition and availability compiled. In addition, the pretreatments used for seaweed fractionation were thoroughly revised as this step is pivotal in a seaweed biorefinery for integral biomass valorization and for enabling biomass-to-biofuel economic feasibility processes. Traditional and emerging technologies were revised, with particular emphasis on green technologies, relating pretreatment not only with the type of biomass but also with the final target product(s) and yields. Current hurdles of marine biomass-to-biofuel processes were pinpointed and discussed and future perspectives on the development of these processes given.
Acrylamide/2-acryloxyethyltrimethyl ammonium chloride copolymers in inverse microemulsion, with a cationic charge density of 60% and a concentration of active matter of 30 wt %, of interest as flocculants have been obtained by inverse microemulsion copolymerization. Interesting inverse microemulsion formulations from both industrial and economical standpoints were selected from pseudoternary phase diagrams. These formulations were polymerized by semicontinuous free radical copolymerization in inverse microemulsion using sodium disulfite and ammonium persulfate as initiators. Influence of initiators and initiator addition conditions (specific flow rate and concentration) on semicontinuous polymerization and final product properties as flocculants have been studied. A strong difference in copolymer solution viscosity has been found when an aqueous solution of sodium disulfite is used as initiator instead of sodium disulfite/ammonium persulfate couple redox, specially for low sodium disulfite solution feeding flow.
Corn stover is the most produced byproduct from maize worldwide. Since it is generated as a residue from maize harvesting, it is an inexpensive and interesting crop residue to be used as a feedstock. An ecologically friendly pretreatment such as autohydrolysis was selected for the manufacture of second-generation bioethanol from corn stover via whole-slurry fermentation at high-solid loadings. Temperatures from 200 to 240 °C were set for the autohydrolysis process, and the solid and liquid phases were analyzed. Additionally, the enzymatic susceptibility of the solid phases was assessed to test the suitability of the pretreatment. Afterward, the production of bioethanol from autohydrolyzed corn stover was carried out, mixing the solid with different percentages of the autohydrolysis liquor (25%, 50%, 75%, and 100%) and water (0% of liquor), from a total whole slurry fermentation (saving energy and water in the liquid–solid separation and subsequent washing of the solid phase) to employing water as only liquid medium. In spite of the challenging scenario of using the liquor fraction as liquid phase in the fermentation, values between 32.2 and 41.9 g ethanol/L and ethanol conversions up to 80% were achieved. This work exhibits the feasibility of corn stover for the production of bioethanol via a whole-slurry fermentation process.
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