The hydrogen sorption capacity of carbon nanostructures was for several years a very controversial subject. Theoretical models have been published demonstrating a great potential for a large hydrogen sorption capacity of carbon nanostructures. Here we present a simple empirical model where condensation of hydrogen as a monolayer at the surface of nanotubes as well as bulk condensation in the cavity of the tube is assumed. The maximum potential amount of hydrogen absorbed according to the model was calculated to be 2.28 × 10 −3 mass % S[m 2 g −1 ] = 3.0 mass % for the adsorption of a monolayer hydrogen at the surface. The condensation of hydrogen in the cavity of the tube leads to a potential absorption for single wall nanotubes starting at 1.5 mass % and increasing with the diameter of the tubes. The experimentally measured hydrogen capacity of the nanotube samples correlates with the B.E.T. specific surface area. The slope of the linear relationship is 1.5 × 10 −3 mass %/m 2 g −1 . Therefore, the extrapolated maximum discharge capacity of a carbon sample is 2 mass %. Furthermore, it can be concluded, that the hydrogen sorption mechanism is related to the surface of the sample, i.e. a surface adsorption process.
The challenge in the research on hydrogen storage materials is to pack hydrogen atoms or molecules as close as possible. Hydrogen absorbed in metals can reach a density of more than 150 kg m −3 (e.g. Mg 2 FeH 6 or Al(BH 4 ) 3 ) at atmospheric pressure. For metallic hydrides, however, due to the large atomic mass of the transition metals the gravimetric hydrogen density is limited to less than 5 mass%. Nanostructured carbon materials, e.g. carbon nanotubes or high surface area graphite absorb hydrogen at liquid nitrogen proportional to the specific surface area 1.5 mass%/1000 m 2 g −1 . Light weight group three metals, e.g. Al, B, are able to bind four hydrogen atoms and form together with an alkali metal an ionic or at least partially covalent compound. The complex hydrides can only be cycled in as nanostructured materials.
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