Optical temperature sensing using upconversion fluorescence emission in Er3+/Yb3+-codoped Ga2S3:La2O3 chalcogenide glass excited at 1.06 μm is reported. Temperature measurements in the region of 20–225 °C with a resolution of approximately 0.5 °C using excitation powers of a few tens of milliwatts were obtained. The temperature sensing mechanism is independent of variations in the excitation intensity, possible fluctuations of transmission, and utilizes a simple signal detection and processing system. The results also revealed that the glass host material plays an important role in the performance of the sensing system.
Thermally induced threefold infrared-to-visible upconversion emission enhancement in Er3+/Yb3+-codoped Ga2S3:La2O3 chalcogenide glasses excited at 1.064 μm is reported. The times three upconversion efficiency enhancement was achieved by heating the sample in the temperature range of 23–155 °C, and is assigned to the temperature-dependent multiphonon-assisted anti-Stokes sideband excitation process of the ytterbium sensitizer. A theoretical analysis based upon rate equations considering the sensitizer absorption cross section as a function of the phonon occupation number in the host material exhibited very good agreement with experimental data.
Blue luminescence emission around 480 nm through cooperative upconversion from pairs of Yb 3ϩ ions implanted into 60TeO 2 -10GeO 2 -10K 2 O-10Li 2 O-10Nb 2 O 5 tellurite glasses and excited by a cw laser at 1.064 m is demonstrated. Cooperative luminescence emission enhancement owing to the temperature dependent multiphonon-assisted anti-Stokes excitation process of the ytterbium ions is also observed. The experimental results revealed a fourfold enhancement in the cooperative luminescence emission when the sample was heated in the temperature range of 20°C-260°C. The thermally induced enhancement is assigned to the effective absorption cross-section for the ytterbium ions which is an increasing function of the medium temperature.
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