In Part I, the processing, microstructure and mechanical properties of three silicon nitride-based ceramics were examined and their non-toxicity was demonstrated. In this Part II, some features critical to biomedical applications were investigated: (i) the wetting behaviour against aqueous media, including physiological solutions; (ii) the chemical stability in water and in physiological solutions; and (iii) the wear resistance, measured under experimental procedures that simulate the conditions typical of the hip joint prosthesis. The results confirmed that silicon nitride may serve as a biomaterial for bone substitution in load bearing prosthesis.
Effect of cerium pretreatment on the corrosion inhibition characteristics of AA6061 T6 alloy-10% Al 2 O 3 metal-matrix composite was investigated in aerated 3.5% NaCl solution after different immersion times ranging between 1 and 60 days at room temperature. Series of specimens were prepared under the following conditions: as-polished; directly treated in CeCl 3 ; alkaline etching followed by CeCl 3 treatment; immersion in boiling water followed by CeCl 3 treatment; and alkaline etching followed by immersion in boiling water and then CeCl 3 treatment. Electrochemical impedance spectroscopy (EIS) was used to investigate the corrosion behaviour of treated and untreated specimens. The EIS was measured by perturbing the free corrosion potential of the specimens with 10 mV a.c. with a frequency decreasing from 10 mHz to 65 kHz. Polarization tests were used to investigate the perfect passivity domain after corrosion. Optical microscopy and SEM were used to investigate the occurrence of localized corrosion due to chloride ion attack. Specimens untreated, directly treated in CeCl 3 and alkaline etched followed by CeCl 3 treatment suffered from pitting as well as crevice corrosion after 30 days of immersion in NaCl. Conversely, the specimens after alkaline etching followed by oxide thickening in boiling water before cerium treatment showed promising corrosion protection even after 60 days of immersion in NaCl. The degree of protection depends to a high extent on the specimen preparation prior to cerium pretreatment.
A recent analysis of the Fermi Large Area Telescope data provided evidence for a high-intensity emission of high-energy gamma rays with a E −2 spectrum from two large areas, spanning 50 • above and below the Galactic centre (the "Fermi bubbles"). A hadronic mechanism was proposed for this gamma-ray emission making the Fermi bubbles promising source candidates of high-energy neutrino emission. In this work Monte Carlo simulations regarding the detectability of high-energy neutrinos from the Fermi bubbles 4 with the future multi-km 3 neutrino telescope KM3NeT in the Mediterranean Sea are presented. Under the hypothesis that the gamma-ray emission is completely due to hadronic processes, the results indicate that neutrinos from the bubbles could be discovered in about one year of operation, for a neutrino spectrum with a cutoff at 100 TeV and a detector with about 6 km 3 of instrumented volume. The effect of a possible lower cutoff is also considered.
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