The Sun is an active star that can launch large eruptions of magnetised plasma into the heliosphere, called coronal mass ejections (CMEs). These ejections can drive shocks that accelerate particles to high energies, often resulting in radio emission at low frequencies (<200 MHz). To date, the relationship between the expansion of CMEs, shocks and particle acceleration is not well understood, partly due to the lack of radio imaging at low frequencies during the onset of shock-producing CMEs. Here, we report multi-instrument radio, white-light and ultraviolet imaging of the second largest flare in Solar Cycle 24 (2008-present) and its associated fast CME (3038±288 km/s). We identify the location of a multitude of radio shock signatures, called herringbones, and find evidence for shock accelerated electron beams at multiple locations along the expanding CME. These observations support theories of non-uniform, rippled shock fronts driven by an expanding CME in the solar corona.Particles accelerated in collisionless shocks are of particular interest in space plasmas and are often associated with CMEs from the Sun. Shocks and related high-energy particles can propagate through the heliosphere, influencing planetary ionospheres and atmospheres, and also affecting technological systems at Earth (for a review see [1]). Such processes are not limited to our solar system; other stars are expected to produce even larger CMEs, stronger shocks and more powerful particle acceleration [2]. Particles accelerated by these powerful eruptions from other stars can even affect the habitability of exoplanets [3]. Since observations of stellar eruptions are very limited, studying particle acceleration at the Sun is of crucial importance for understanding these processes universally.Fast CMEs (with speeds up to ∼3,500 km/s [4,5]) are powerful drivers of plasma shocks that can accelerate particles up to relativistic speeds producing bursts of plasma emission at radio wavelengths [6]. The most obvious manifestations of shocks at radio wavelengths on the Sun are a class of radio bursts, Type II bursts, mostly observed at frequencies <150 MHz [7,8,9]. They usually show two emission lanes slowly drifting to lower frequencies in dynamic spectra, with a 2:1 frequency ratio representing emission at the fundamental and harmonic plasma frequency. Type II bursts have been imaged on multiple occasions showing sources closely associated with CMEs [8,10,11], while simulations and CME reconstructions closely associate Type IIs with CME shocks [12,13]. In some cases, 'bursty' signatures of individual electron beams accelerated by CME shocks can be identified in 2 dynamic spectra superimposed on Type II bursts [14]. These electron beam signatures, called 'herringbones', are identified as narrow bursts of radiation drifting towards higher and lower frequencies, categorised as distinct emission from the accompanying Type II burst [15,16], and sometimes even observed without a Type II [15,17]. Despite the wealth of publications on Type II bursts, there ha...

Aims. The Spectrometer Telescope for Imaging X-rays (STIX) on Solar Orbiter is a hard X-ray imaging spectrometer, which covers the energy range from 4 to 150 keV. STIX observes hard X-ray bremsstrahlung emissions from solar flares and therefore provides diagnostics of the hottest (⪆10 MK) flare plasma while quantifying the location, spectrum, and energy content of flare-accelerated nonthermal electrons. Methods. To accomplish this, STIX applies an indirect bigrid Fourier imaging technique using a set of tungsten grids (at pitches from 0.038 to 1 mm) in front of 32 coarsely pixelated CdTe detectors to provide information on angular scales from 7 to 180 arcsec with 1 keV energy resolution (at 6 keV). The imaging concept of STIX has intrinsically low telemetry and it is therefore well-suited to the limited resources available to the Solar Orbiter payload. To further reduce the downlinked data volume, STIX data are binned on board into 32 selectable energy bins and dynamically-adjusted time bins with a typical duration of 1 s during flares. Results. Through hard X-ray diagnostics, STIX provides critical information for understanding the acceleration of electrons at the Sun and their transport into interplanetary space and for determining the magnetic connection of Solar Orbiter back to the Sun. In this way, STIX serves to link Solar Orbiter’s remote and in-situ measurements.

Aryl-and heteroaryl-nitrenes can take part in intra-and intermolecular reactions in both of their possible electronic states (triplet and singlet). In this review we have endeavored to highlight recent synthetic uses of these reactive intermediates as well as draw attention to avenues open to further exploration in this field. Singlet arylnitrenes will interact with suitable orthopositioned substituents to give a variety of fused azoles, some in excellent yield. In suitable solvents and in presence of amines and alcohols, phenylnitrenes undergo ring expansion to azepines which can also occur in nitrenes of certain fused bicyclic aromatics (naphthalene, quinoline, isoquinoline, benzo[b]thiophene). The latter nitrenes may also give rise to o-diamines which are useful starters for further heterocyclic synthesis. Triplet arylnitrenes (usually regarded as having only a nuisance effect in synthetic work) may also be utilized in practicable heterocyclic syntheses within a suitable molecular framework. Decomposition of aryl azides in a mixture of an organic and polyphosphoric acid leads to fused oxazoles. The mechanism is discussed for all the reactions considered.

Solar flares are extremely energetic phenomena in our Solar System. Their impulsive, often drastic radiative increases, in particular at short wavelengths, bring immediate impacts that motivate solar physics and space weather research to understand solar flares to the point of being able to forecast them. As data and algorithms improve dramatically, questions must be asked concerning how well the forecasting performs; crucially, we must ask how to rigorously measure performance in order to critically gauge any improvements. Building upon earlier-developed methodology (Barnes et al. 2016, Paper I), international representatives of regional warning centers and research facilities assembled in 2017 at the Institute for Space-Earth Environmental Research, Nagoya University, Japan to -for the first time -directly compare the performance of operational solar flare forecasting methods. Multiple quantitative evaluation metrics are employed, with focus and discussion on evaluation methodologies given the restrictions of operational forecasting. Numerous methods performed consistently above the "no skill" level, although which method scored top marks is decisively a function of flare event definition and the metric used; there was no single winner. Following in this paper series we ask why the performances differ by examining implementation details (Leka et al. 2019, Paper III), and then we present a novel analysis method to evaluate temporal patterns of forecasting errors in (Park et al. 2019, Paper IV). With these works, this team presents a well-defined and robust methodology for evaluating solar flare forecasting methods in both research and operational frameworks, and today's performance benchmarks against which improvements and new methods may be compared.

Solar flares often display pulsating and oscillatory signatures in the emission, known as quasi-periodic pulsations (QPP). QPP are typically identified during the impulsive phase of flares, yet in some cases, their presence is detected late into the decay phase. Here, we report extensive fine structure QPP that are detected throughout the large X8.2 flare from 2017 September 10. Following the analysis of the thermal pulsations observed in the GOES/XRS and the 131Å channel of SDO/AIA, we find a pulsation period of ∼65 s during the impulsive phase followed by lower amplitude QPP with a period of ∼150 s in the decay phase, up to three hours after the peak of the flare. We find that during the time of the impulsive QPP, the soft X-ray source observed with RHESSI rapidly rises at a velocity of approximately 17 kms −1 following the plasmoid/coronal mass ejection (CME) eruption. We interpret these QPP in terms of a manifestation of the reconnection dynamics in the eruptive event. During the long-duration decay phase lasting several hours, extended downward contractions of collapsing loops/plasmoids that reach the top of the flare arcade are observed in EUV. We note that the existence of persistent QPP into the decay phase of this flare are most likely related to these features. The QPP during this phase are discussed in terms of MHD wave modes triggered in the post-flaring loops.

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Context. Type II radio bursts are evidence of shocks in the solar atmosphere and inner heliosphere that emit radio waves ranging from sub-meter to kilometer lengths. These shocks may be associated with coronal mass ejections (CMEs) and reach speeds higher than the local magnetosonic speed. Radio imaging of decameter wavelengths (20-90 MHz) is now possible with the Low Frequency Array (LOFAR), opening a new radio window in which to study coronal shocks that leave the inner solar corona and enter the interplanetary medium and to understand their association with CMEs. Aims. To this end, we study a coronal shock associated with a CME and type II radio burst to determine the locations at which the radio emission is generated, and we investigate the origin of the band-splitting phenomenon. Methods. The type II shock source-positions and spectra were obtained using 91 simultaneous tied-array beams of LOFAR, and the CME was observed by the Large Angle and Spectrometric Coronagraph (LASCO) on board the Solar and Heliospheric Observatory (SOHO) and by the COR2A coronagraph of the SECCHI instruments on board the Solar Terrestrial Relation Observatory (ST EREO). The 3D structure was inferred using triangulation of the coronographic observations. Coronal magnetic fields were obtained from a 3D magnetohydrodynamics (MHD) polytropic model using the photospheric fields measured by the Heliospheric Imager (HM I) on board the Solar Dynamic Observatory (SDO) as lower boundary. Results. The type II radio source of the coronal shock observed between 50 and 70 MHz was found to be located at the expanding flank of the CME, where the shock geometry is quasi-perpendicular with θBn ∼ 70 • . The type II radio burst showed first and second harmonic emission; the second harmonic source was cospatial with the first harmonic source to within the observational uncertainty. This suggests that radio wave propagation does not alter the apparent location of the harmonic source. The sources of the two split bands were also found to be cospatial within the observational uncertainty, in agreement with the interpretation that split bands are simultaneous radio emission from upstream and downstream of the shock front. The fast magnetosonic Mach number derived from this interpretation was found to lie in the range 1.3-1.5. The fast magnetosonic Mach numbers derived from modelling the CME and the coronal magnetic field around the type II source were found to lie in the range 1.4-1.6.