A time-resolved thermal mirror method for measurements of absolute thermo-optical-mechanical properties of low absorbing solids is presented. The thermoelastic equation for the surface displacement and an analytical expression for the probe beam intensity at the detector plane were derived. Experimental proofs were performed in an optical glass and the fitted parameters are in good agreement with previous literature data for thermal, optical, and mechanical properties, suggesting that the method is a useful tool for the characterization of a wide range of transparent materials.

A general and complete theoretical model of the time-resolved thermal mirror method for the measurement of thermo-optical-mechanical properties of solid materials is developed. The laser-induced temperature profile in a sample and its thermoelastic surface displacement are derived. The center intensity of a probe beam at the detector plane is calculated using the Fresnel diffraction theory. Additionally, simplified models for high and low optical absorption samples are presented, and the suitability of the simplified models is also analyzed. The influence of experimental parameters on the sensitivity of the thermal mirror method is discussed for the optimization of the experimental apparatus. The presented model and the experimental technique can be used to quantitatively determine the physical properties of transparent and opaque solids.

We report a theoretical model and experimental results for laser-induced local heating in liquids, and propose a method to detect and quantify the contributions of photochemical and Soret effects in several different situations. The time-dependent thermal and mass diffusion equations in the presence and absence of laser excitation are solved. The two effects can produce similar transients for the laser-on refractive index gradient, but very different laser-off behavior. The Soret effect, also called thermal diffusion, and photochemical reaction contributions in photochemically reacting aqueous Cr(VI)-diphenylcarbazide, Eosin Y, and Eosin Y-doped micellar solutions, are decoupled in this work. The extensive use of lasers in various optical techniques suggests that the results may have significance extending from physical-chemical to biological applications.

We consider the time dependence of the absorption coefficient due to the photoinduced chemical reaction (PCR) and species diffusion to calculate the temperature rise in the thermal-lens (TL) effect. The TL signal at the detector plane is also calculated. This theoretical approach removes the restriction that the PCR time constant is much greater than the characteristic TL time constant, which was assumed in a previously published model. Hydrocarbon fuel and aqueous Cr(VI) samples are investigated, and quantitative experimental results for the thermal, optical, and PCR properties are obtained. While similar results were obtained for the Cr(VI) solution using the previous and present models, the relative difference between the PCR time constants extracted from the same experimental data for a hydrocarbon fuel sample is found to be more than 220%. This demonstrates the significant difference of the two models.

Nanoscale surface displacement is used to determine thermo-optical–mechanical properties of high absorbing solids by means of the time-resolved thermal mirror method. The thermoelastic equation for the surface displacement and an expression for the probe beam intensity at the detector plane were derived. Experiments were performed in a high absorbing TiO2-doped low silica calcium aluminosilicate glass, and obtained the valuable values of the fluorescence quantum efficiency and thermal properties. The results indicate that this method is reliable for the characterization of semitransparent, high absorbing, and opaque materials.

Thermal lens spectroscopy is a highly sensitive and versatile photothermal technique for material analysis, providing optical and thermal properties. To use less expensive multimode non-Gaussian lasers for quantitative analysis of low-absorption materials, this Letter presents a theoretical model for time-resolved mode-mismatched thermal lens spectroscopy induced by a cw laser with a top-hat profile. The temperature profile in a sample was calculated, and the intensity of the probe beam center at the detector plane was also derived using the Fresnel diffraction theory. Experimental validation was performed with glass samples, and the results were found well consistent with literature values of the thermo-optical properties of the samples.

A theoretical model was developed for time-resolved thermal mirror spectroscopy under top-hat cw laser excitation that induced a nanoscale surface displacement of a low absorption sample. An additional phase shift to the electrical field of a TEM(00) probe beam reflected from the surface displacement was derived, and Fresnel diffraction theory was used to calculate the propagation of the probe beam. With the theory, optical and thermal properties of three glasses were measured, and found to be consistent with literature values. With a top-hat excitation, an experimental apparatus was developed for either a single thermal mirror or a single thermal lens measurement. Furthermore, the apparatus was used for concurrent measurements of thermal mirror and thermal lens. More physical properties could be measured using the concurrent measurements.

Temperature dependence of the thermo-optical properties of water determined by thermal lens spectrometry Rev. Sci. Instrum. 74, 808 (2003); 10.1063/1.1517161 Time resolved thermal lens in edible oils Rev. Sci. Instrum. 74, 694 (2003); 10.1063/1.1512776 High-sensitivity absorption measurement in water and glass samples using a mode-mismatched pump-probe thermal lens method Appl. Phys. Lett. 78, 3415 (2001); 10.1063/1.1375835Pump-probe thermal lens near-infrared spectroscopy and Z-scan study of zinc (tris) thiourea sulfate