Abstract. Fundamental processes leading to the erosion of hydrocarbon films due to energetic argon ions and hydrogen atoms have been investigated using molecular dynamics simulations. A generic mechanism has been identified for carbon erosion due to energetic (150 eV) argon ions in the presence of sub-eV hydrogen atoms. This surface erosion process, which we call hydrogen enhanced physical sputtering (HEPS), is primarily a physical sputtering mechanism, enhanced due to the screening effect of hydrogen atoms. The energetic argon ions create open bonds within their penetration range. The hydrogen atoms passivate the open bonds created within the first few atomic layers. Subsequent ion bombardment causes the breaking of C-C bonds within and beyond the H penetration range. The steric effect of H atoms bound to the top layer of carbon atoms prevents the re-attachment of the broken bonds, and this leads to unsaturated molecule emission from the surface. The kinetic energy of the emitted molecules is above thermal energy and the emission takes place within 5 ps after the ion impact.
The effect of the primary knock-on atom (PKA) spectrum in radiation damage and the subsequent defect structure formation and their impact in deuterium (D) trapping has been investigated using computer simulations and surrogate ion irradiation experiments. The neutron spectrum for an 'ITER-like' divertor shape and parameters has been generated using ATTILA and SPECTER codes to identify the relevant PKA energies. It has been observed that 10 MeV boron (B) produces a PKA spectrum similar to that obtained from a reactor-like neutron spectrum. Experiments have been carried out with ions of gold (Au), B, helium (He) and D with energies ranging from 0.1 MeV-80 MeV for a fluence range of 1.3 × 10 18 ions m −2 -5 × 10 21 ions m −2 , and distinctly different PKA spectra have been produced. While 80 MeV Au ions produced dense and small clusters of interstitial defects (<10 nm), B produced large dislocation loops up to 60 nm in size. At room temperature, the imprint of the cascade is well captured by the vacancies due to their low mobility, and the vacancy defects observed in Au and B irradiation showed significant differences. Molecular dynamics simulations show that at PKA energies exceeding 150 keV, the fragmentation of the cascades takes place, which tends to limit the size of individual defects in the case of 80 MeV Au irradiation. A mechanism based on the competitive capture of mobile interstitials has been proposed to explain the observed large dislocation loops as well as dislocation lines in different irradiation experiments.
Plasma neutralisers promise increased neutralisation efficiency of negative ion beams in neutral beam injection (NBI) beamlines compared with gas neutralisers. It has been suggested that, in the presence of an electron-confining magnetic cusp field along all neutraliser walls, the beam itself could ionise the neutraliser gas sufficiently to take advantage of this effect, avoiding the added complexity of external power coupling to the neutraliser. These predictions come from a zero-dimensional model by Surrey and Holmes [1] and Turner and Holmes [2]. We have revisited and modified this model by introducing slowing-down energy distributions for stripped and Rudd electrons, including electron impact dissociation as an electron energy loss channel and taking into account dissociative recombination of molecular ions with electrons. Including the latter effect reduces the predicted plasma density by about a factor of four and the achievable neutralisation yield from ∼ 80 % to 68 % in the case of a negative deuterium ion beam with an energy of 1 MeV and a current of 40 A. With this revised model we estimate the expected performance of potential beam-driven plasma neutralisers (BDPN) on a variety of existing negative ion beam test facilities for neutral beam injection. Based on these results, we conclude that the most suitable proof-of-principle experiment would be a dedicated chamber, ideally of the same dimensions and with the same magnetic cusp configuration as a BDPN for the DEMO NBI, in which the plasma is not created primarily by the fast electrons stripped from the beam ions, but by electrons of similar current and energy emitted from biased filaments.
Surface-shifted deuterium profiles are re-examined in deuterium-ion irradiation experiments by using a combined experimental and modelling approach. Recrystallized tungsten foil samples were irradiated with energetic deuterium ions and the defect and deuterium depth profiles were studied using positron annihilation spectroscopy and secondary ion mass spectroscopy. We report direct experimental evidence of trapping of deuterium at the vacancies created by the deuterium ions themselves during the implantation by using positron annihilation studies. The deuterium profile is simulated using a Monte-Carlo diffusion model by taking into account the defect-aided diffusion of deuterium due to the local strain field created by the vacancies. The simulations also elucidate the role of the anisotropy in the diffusion and trapping of deuterium in ion-implantation experiments in metals.
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