Heavy metal remediation of aqueous streams is of special concern due to recalcitrant and persistency of heavy metals in environment. Conventional treatment technologies for the removal of these toxic heavy metals are not economical and further generate huge quantity of toxic chemical sludge. Agricultural waste materials being economic and ecofriendly due to their unique biochemical composition, availability in abundance, renewable, low in cost and more efficient are seem to be viable option for heavy metal remediation. The major advantages of biosorption over conventional treatment methods include: low cost, high efficiency, minimization of chemical or biological sludge, regeneration of biosorbents and possibility of metal recovery. It is well known that cellulosic waste materials can be obtained and employed as cheap adsorbents and their performance to remove heavy metal ions can be affected upon chemical treatment. In general, chemically modified plant wastes exhibit higher adsorption capacities than unmodified forms. The functional groups present in agricultural waste biomass viz. acetamido, alcoholic, carbonyl, phenolic, amido, amino, sulphydryl groups etc. Have affinity for heavy metal ions to form metal complexes or chelates. Some of the treated adsorbents show good adsorption capacities for Cd, Cu, Pb, Zn and Ni. Rice husk as a low-value agricultural by-product can be made into sorbent materials which are used in heavy metal removal. The mechanism of biosorption process includes chemisorptions, complexation, adsorption on surface, diffusion through pores and ion exchange etc. Agricultural residues are lignocelluloses substances which contain three main structural components: hemicelluloses, cellulose and lignin. Lignocellulosic materials also contain extractives. Generally, three main components have high molecular weights and contribute much mass, while the extractives is of small molecular size, and available in little quantity, which announce in heavy metal removal.
Hussain sagar lake, a historical lake which was built in 1562 by Hussain Shaw Wali is situated in the heart of Hyderabad city, India. Earlier up to 1930's, it was the major water source to meet drinking and irrigation requirements for both twin cities of Hyderabad and Secunderabad. Now this lake turned to virtual garbage bin with no adequate treatment for wastewater loads originated from point and non point sources. Therefore the lake loses the capability of self purification system which was an important factor that depends on the maximum uptake of oxygen from the atmosphere. Multiple projects were undertaken by the concerned authorities for the improvement of Hussain sagar lake and its catchment area. Recently With referring to the Lake health status, In 2006, HMDA, a governing body set up by Andhra Pradesh Government, initiated "Hussainsagar Lake and Catchment Area Improvement project" and set up STPs and wastewater interception and diversion structures. It also installed fountains to aerate the lake to improve its water quality as well as to add beauty. But these measures are lying ineffective to manage wastewater loads. This paper discusses that the Hussain Sagar lake water body over decades, has been polluted adversely from discharging of organic and inorganic pollutants through open drains as well as point and non point sources and also presents various measures had taken to rejuvenate Hussain Sagar Lake to its past glory.
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