We present simulations and experiments of drainage processes in a micro-model. A direct numerical simulation is introduced which is capable of describing wetting phenomena on the pore scale. A numerical smoothed particle hydrodynamics model was developed and used to simulate the two-phase flow of immiscible fluids. The experiments were performed in a micro-model which allows the visualization of interface propagation in detail. We compare the experiments and simulations of a quasistatic drainage process and pure dynamic drainage processes. For both, simulation and experiment, the interfacial area and the pressure at the inflow and outflow are tracked. The capillary pressure during the dynamic drainage process was determined by image analysis.
The performance of the gas diffusion electrode (GDE) is crucial for technical processes like chlorine-alkali electrolysis. The function of the GDE is to provide an intimate contact between gaseous reactants, the solid catalyst, and the liquid electrolyte. To accomplish this, the GDE is composed of wetting and non-wetting materials to avoid electrolyte breakthrough. Knowledge of the spatial distribution of the electrolyte in the porous structure is a prerequisite for further improvement of GDE. Therefore, the ability of the electrolyte to imbibe into the porous electrode is studied by direct numeric simulations in a reconstructed porous electrode. The information on the geometry, including the information on silver and PTFE distribution of the technical GDE, is extracted from FIB/SEM imaging including a segmentation into the different phases. Modeling of wetting phenomena inside the GDE is challenging, since surface tension and wetting of the electrolyte on silver and PTFE surfaces must be included in a physically consistent manner. Recently, wetting was modeled from first principles on the continuum scale by introducing a contact line force. Here, the newly developed contact line force model is employed to simulate two-phase flow in the solid microstructures using the smoothed particle hydrodynamics (SPH) method. In this contribution, we present the complete workflow from imaging of the GDE to dynamic SPH simulations of the electrolyte intrusion process. The simulations are used to investigate the influence of addition of non-wetting PTFE as well as the application of external pressure differences between the electrolyte and the gas phase on the intrusion process.
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