The hydrogen bonded complexes involving primary amines (propyl amine, butyl amine and pentyl amine) and decanol in carbon tetrachloride were studied at 301k. The dipole moment of the complex obtained from the dielectric measurements using by Huysken's method based on Onsager theory. The dipolar increment and enthalpy changes during fond formation were evaluated from the complex dipole moment. The results were interpreted in terms of interactions. The and values indicate the interaction due to polarization only.
The Kirkwood correlation factor (g) of binary mixtures of amyl acetate and isoamyl acetate with in benzene, carbon tetrachloride and acetone were obtained from a measurement of dielectric constant, density and refractive index at 301 K. The fluid structure of amyl acetate and isoamyl acetate is discussed. In amyl acetate and isoamyl acetate in carbon tetrachloride, benzene and acetone, a dimeric linear chain with the individual dipoles more or less parallel orientation is preferred. In amyl acetate, with increase of concentration, the value of g tending to unity indicates the parallel orientation.
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