Summary
1. The non‐conjugated unsaturated fatty acid esters react with maleic anhydride at 200° C. or above.
2. At 200° C., methyl oleate reacts with almost 1 mole, methyl linoleate with 2 moles, and methyl linolenate with 2.5 moles of maleic anhydride, when an excess of anhydride is present. Methyl stearate reacts negligibly.
3. Methyl oleate reacts without affecting unsaturation.
4. The first molecule of anhydride reacting with methyl linoleate reacts mostly to saturate one double bond, while the second one adds on without affecting unsaturation.
5. The first two molecules of anhydride reacting with methyl linolenate react mostly to saturate one double bond each, while the third molecule adds on without affecting unsaturation.
6. The possible structures of the reaction products have been discussed.
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