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An unanticipated superparamagnetic response has been observed in cobalt ferrite materials after thermal treatment under inert atmosphere. Cobalt ferrite particles were prepared via normal micelle precipitation that typically yields Co x Fe 3−x O 4 nanoparticles ͑x = 0.6− 1.0͒. While samples thermally treated under oxygen show majority spinel phase formation, annealing in nitrogen gas yields materials consisting of Co-Fe alloy, FeS, and CoFe 2 O 4 spinel. After thermal treatment, thermomagnetic studies reveal composition-insensitive, but highly treatment-sensitive, saturation magnetization, coercivity, blocking temperature, and Verwey transition temperature dependence. Extremely high saturation magnetization ͑159 emu/g͒ with low coercivity ͑31 Oe͒ was observed for one of the treated compositions, which drastically deviates from prototypical cobalt ferrite with large magnetocrystalline anisotropy. We attribute such unique magnetic response to Co-Fe alloy coexisting with FeS and CoFe 2 O 4 spinel where the diameter of the metallic phase is below the superparamagnetic limit. While thermal treatment in nitrogen was not anticipated to yield Co-Fe alloy, chemisorbed surfactant molecules ͑i.e., sodium dodecylsulfate͒ are postulated to act as reducing agents in the present scenario.
Electromagnetic shields and flux concentrators for magnetic sensors could utilize flexible and insulating composites applied using simple thin film deposition methods such as dip-coating, spin-coating, spraying, etc. As the first step towards development of composites with superior performance, efforts focused on isolating nanoparticles with large magnetizations under low fields. In this paper, we provide the results of proof-of-concept studies for two systems: metal-functionalized silicone-based materials (metal-silicone); and, Co-ferrite (Co2+1−xFe2+xFe3+2O4) nanoparticles. The metal-silicone materials studied included a polysiloxane that contained a pendant ferrocene where an optimum saturization magnetization of 5.9 emu/g (coercivity = 11 Oe) was observed. Co-ferrite nanoparticle samples prepared in this study showed unprecendented saturation magnetization (i.e., Ms > 150 emu/g) with low coercivity (Hc ∼ 10 Oe) at room temperature and offer potential application as flux concentrators.
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