[1] This paper provides a review of stratosphere-troposphere exchange (STE), with a focus on processes in the extratropics. It also addresses the relevance of STE for tropospheric chemistry, particularly its influence on the oxidative capacity of the troposphere. After summarizing the current state of knowledge, the objectives of the project Influence of Stratosphere-Troposphere Exchange in a Changing Climate on Atmospheric Transport and Oxidation Capacity (STACCATO), recently funded by the European Union, are outlined. Several papers in this Journal of Geophysical ResearchAtmospheres special section present the results of this project, of which this paper gives an overview. STACCATO developed a new concept of STE in the extratropics, explored the capacities of different types of methods and models to diagnose STE, and identified their various strengths and shortcomings. Extensive measurements were made in central Europe, including the first monitoring over an extended period of time of beryllium-10 ( 10 Be), to provide a suitable database for case studies of stratospheric intrusions and for model validation. Photochemical models were used to examine the impact of STE on tropospheric ozone and the oxidizing capacity of the troposphere. Studies of the present interannual variability of STE and projections into the future were made using reanalysis data and climate models.

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[1] This paper presents results of a 1-year simulation of the transport of six passive tracers, released over the continents according to an emission inventory for carbon monoxide (CO). Lagrangian concepts are introduced to derive age spectra of the tracer concentrations on a global grid in order to determine the timescales and pathways of pollution export from the continents. Calculating these age spectra is equivalent to simulating many (quasi continuous) plumes, each starting at a different time, which are subsequently merged. Movies of the tracer dispersion have been made available on an Internet website. It is found that emissions from Asia experience the fastest vertical transport, whereas European emissions have the strongest tendency to remain in the lower troposphere. European emissions are transported primarily into the Arctic and appear to be the major contributor to the Arctic haze problem. Tracers from an upwind continent first arrive over a receptor continent in the upper troposphere, typically after some 4 days. Only later foreign tracers also arrive in the lower troposphere. Assuming a 2-day lifetime, the domestic tracers dominate total tracer columns over all continents except over Australia where foreign tracers account for 20% of the tracer mass. In contrast, for a 20-day lifetime even continents with high domestic emissions receive more than half of their tracer burden from foreign continents. Three special regions were identified where tracers are transported to, and tracer dilution is slow. Future field studies therefore should be deployed in the following regions: (1) In the winter, the Asia tracer accumulates over Indonesia and the Indian Ocean, a region speculated to be a stratospheric fountain.

This study presents the first climatology of so-called warm conveyor belts (WCBs), strongly ascending moist airstreams in extratropical cyclones that, on the time scale of 2 days, rise from the boundary layer to the upper troposphere. The climatology was constructed by using 15 yr (1979-93) of reanalysis data and calculating 355 million trajectories starting daily from a 1Њ ϫ 1Њ global grid at 500 m above ground level (AGL). WCBs were defined as those trajectories that, during a period of 2 days, traveled northeastward and ascended by at least 60% of the zonally and climatologically averaged tropopause height. The mean specific humidity at WCB starting points in different regions varies from 7 to 12 g kg Ϫ1. This moisture is almost entirely precipitated out, leading to an increase of potential temperature of 15-22 K along a WCB trajectory. Over the course of 3 days, a WCB trajectory produces, on average, about four (six) times as much precipitation as a global (extratropical) average trajectory starting from 500 m AGL. WCB starting points are most frequently located between approximately 25Њ and 45ЊN and between about 20Њ and 45ЊS. In the Northern Hemisphere (NH), there are two distinct frequency maxima east of North America and east of Asia, whereas there is much less zonal variability in the Southern Hemisphere (SH). In the NH, WCBs are almost an order of magnitude more frequent in January than in July, whereas in the SH the seasonal variation is much weaker. In order to study the relationship between WCBs and cyclones, an independent cyclone climatology was used. Most of the WCBs were found in the vicinity of a cyclone center, whereas the reverse comparison revealed that cyclones are normally accompanied by a strong WCB only in the NH winter. In the SH, this is not the case throughout the year. Particularly around Antarctica, where cyclones are globally most frequent, practically no strong WCBs are found. These cyclones are less influenced by diabatic processes and, thus, they are associated with fewer high clouds and less precipitation than cyclones in other regions. In winter, there is a highly significant correlation between the North Atlantic Oscillation (NAO) and the WCB distribution in the North Atlantic: In months with a high NAO index, WCBs are about 12% more frequent and their outflow occurs about 10Њ latitude farther north and 20Њ longitude farther east than in months with a low NAO index. The differences in the WCB inflow regions are relatively small between the two NAO phases. During high phases of the Southern Oscillation, WCBs occur more (less) frequent around Australia (in the South Atlantic).

A diagnostic Lagrangian method to trace the budgets of freshwater fluxes, first described in Part I of this article, is used here to establish source–sink relationships of moisture between earth’s ocean basins and river catchments. Using the Lagrangian particle dispersion model FLEXPART, driven with meteorological analyses, 1.1 million particles, representing the mass of the atmosphere, were tracked over a period of 4 yr. Via diagnosis of the changes of specific humidity along the trajectories, budgets of evaporation minus precipitation (E − P) were determined. For validation purposes, E − P budgets were calculated for 39 river catchments and compared with climatological streamflow data for these rivers. Good agreement (explained variance 87%) was found between the two quantities. The E − P budgets were then tracked forward from all of earth’s ocean basins and backward from the 39 major river catchments for a period of 10 days. As much previous work was done for the Mississippi basin, this basin was chosen for a detailed analysis. Moisture recycling over the continent and moisture transport from the Gulf of Mexico were identified as the major sources for precipitation over the Mississippi basin, in quantitative agreement with previous studies. In the remainder of the paper, global statistics for source–sink relationships of moisture between the ocean basins and river catchments are presented. They show, for instance, the evaporative capacity of monsoonal flows for precipitation over the Ganges and Niger catchments, and the transport of moisture from both hemispheres to supply the Amazon’s precipitation. In contrast, precipitation in northern Eurasia draws its moisture mainly via recycling over the continent. The atmospheric transport of moisture between different ocean basins was also investigated. It was found that transport of air from the North Pacific produces net evaporation over the North Atlantic, but not vice versa. This helps to explain why the sea surface salinity is higher in the North Atlantic than in the North Pacific, a difference thought to be an important driver of the oceans’ thermohaline circulation. Finally, limitations of the method are discussed and possible future developments are outlined.