Recently several sets of values for the critical constants of NaCl and KCl have been published. It is the purpose of this note to compare these values and to present some observations upon the methods by which they were obtained. Carlson, Eyring, and Ree2 (CER) applied the well known method of significant structures
It must be noted that the solution composition was not the same in the polarographic and faradaic rectification measurements. Further, the OH" concentration at the electrode increases with the current for H2 evolution in the polarographic experiments.
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