International audienceHydrous clay minerals detected on the surface of Mars have been interpreted as indicators of the hydrologic and climatic evolution of the planet. The iron- and magnesium-rich clays described in thick, extensive outcrops of Noachian crust have been proposed to originate from aqueous weathering. This would imply that liquid water was stable at the surface of early Mars, presumably when the climate was warmer and wetter. Here we show that iron- and magnesium-rich clays can alternatively form by direct precipitation from residual, water-rich magma-derived fluids. Infrared reflectance spectra from terrestrial lavas from the Mururoa Atoll (French Polynesia) that underwent this precipitation process are similar to those measured for the Noachian crust. Such an origin is also consistent with the D/H ratio of iron- and magnesium-rich clays in some martian meteorites and the widespread presence of these clays in massive basaltic lavas, breccias and regolith. We propose that the progressive degassing of the martian interior over time and the resultant increasingly water-poor magmatic fluids--and not a cooling climate--may explain the absence of clays in Hesperian-aged and more recent formations

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The clay minerals formed in chilled margins and massive crystallized inner parts of three basalt-hawaiite bodies of Mururoa Atoll (French Polynesia) exhibit contrasting textures. Glass alteration textures are observed around fractures crosscutting the quenched margins: Fe-rich clays grow inward into the glass (retreating surface) while Mg-rich clays grow outward (open space). The textures of clay deposits filling the diktytaxitic voids (mesostasis) in the massive inner parts of the three volcanic bodies are different: unoriented clay matrix with embedded euhedral apatite and pyroxene microcrysts (submarine flow); pallisadic clays coating the void walls and the crystal surfaces of apatite and K-feldspar microcrysts (subaerial flow); and clay muffs covering all the apatite needles, with the central part of the void remaining empty (dike). The unoriented texture could result from the alteration of a glass precursor concomitant with the olivine phenocrysts (clay pseudomorphs). However, such an alteration implies important chemical transfers which are not observed. The pallisadic and muff textures form through heterogeneous nucleation on the solid surfaces and crystal growth from a saline solution. No glass precursor existed. As the center of the diktytaxitic voids in the dike is empty, the residual liquid was probably boiling. The amounts of light rare earth elements (LREE), Sr, and the most incompatible elements are greater in clays from diktytaxitic voids relative to the amounts formed in the altered glass of the chilled margins. Thus, diktytaxitic clays formed from a residual liquid which gave either an evolved glass or a saline solution after cooling (fractionation process). The δ18O variation vs. loss on ignition (LOI) indicates that sea water was involved either in rock alteration or magma contamination. This is confirmed by the 87Rb/86Sr ratio of bulk rocks and clay fractions from the quenched and massive inner parts of the three volcanic bodies which do not fit with the 11.5 Ma isochron indicating that the Rb-Sr system was not closed at any stage during the magmatic history.

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The management of clay‐rich soils in agriculture is mainly dependent on their hydromechanical properties that govern their structural evolutions. These structural evolutions are commonly described along the shrinkage curves obtained in a laboratory. Nevertheless, the field survey needs tools of in situ investigations able to characterize the structural profile evolutions of soils through the seasons. This paper presents a method based on the cone penetration and resistivity measurement by penetrometer–salinometer coupling that was gauged in the West Marsh of the French Atlantic Coast. First, the parallel measurements of water and cone resistance (Qd ) profiles in clay dominant soils, characterized by very large ranges of water content (W), allows the calculation of a Perdock's‐type equation that links the Qd profiles and the shrinkage curve of the clay dominant material. Second, thanks to the homogeneity of mineralogy and cationic exchange capacity of the soil, the structure–resistivity relationship was gauged according to the Archie's law taking into account porosity (ϕ), saturation index of the soil (Sat), and the resistivity of the wetting fluid (ρw). The vertical evolutions of structure, resistivity, and cone resistance can be represented in a crossed diagram showing the shrinkage curve–resistivity and Qd profile relationships. Finally, the structural profiles of soils can be modeled from the recorded resistivity and Qd profiles taking into account the ρw

The thermal conductivity measurement by a simplified transient hot-wire technique is applied to geomaterials in order to show the relationships which can exist between effective thermal conductivity, texture, and moisture of the materials. After a validation of the used "one hot-wire" technique in water, toluene, and glass-bead assemblages, the investigations were performed (1) in glassbead assemblages of different diameters in dried, water, and acetone-saturated states in order to observe the role of grain sizes and saturation on the effective thermal conductivity, (2) in a compacted earth brick at different moisture states, and (3) in a limehemp concrete during 110 days following its manufacture. The lime-hemp concrete allows the measurements during the setting, desiccation and carbonation steps. The recorded ΔT/ ln(t) diagrams allow the calculation of one effective thermal conductivity in the continuous and homogeneous fluids and two effective thermal conductivities in the heterogeneous solids. The first one measured in the short time acquisitions (<1 s) mainly depends on the contact between the wire and grains and thus microtexture and hydrated state of the material. The second one, measured for longer time acquisitions, characterizes the mean effective thermal conductivity of the material.

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