The Montreal Protocol on Substances that Deplete the Ozone Layer has been hailed as the most successful environmental treaty ever ( https://www.unenvironment.org/news-and-stories/story/montreal-protocol-triumph-treaty ). Yet, although our main concern about ozone depletion is the subsequent increase in harmful solar UV radiation at the Earth’s surface, no studies to date have demonstrated its effectiveness in that regard. Here we use long-term UV Index (UVI) data derived from high-quality UV spectroradiometer measurements to demonstrate its success in curbing increases in UV radiation. Without this landmark agreement, UVI values would have increased at mid-latitude locations by approximately 20% between the early 1990s and today and would approximately quadruple at mid-latitudes by 2100. In contrast, an analysis of UVI data from multiple clean-air sites shows that maximum daily UVI values have remained essentially constant over the last ~20 years in all seasons, and may even have decreased slightly in the southern hemisphere, especially in Antarctica, where effects of ozone depletion were larger. Reconstructions of the UVI from total ozone data show evidence of increasing UVI levels in the 1980s, but unfortunately, there are no high-quality UV measurements available prior to the early 1990s to confirm these increases with direct observations.

Abstract. The Langley method of calibrating UV multifilter shadow band radiometers (UV-MFRSR) is explored in this paper. This method has several advantages over the traditional standard lamp calibrations: the Sun is a free, universally available, and very constant source, and nearly continual automated field calibrations can be made. Although 20 or so Langley events are required for an accurate calibration, the radiometer remains in the field during calibration. Difficulties arise as a result of changing ozone optical depth during the Langley event and the breakdown of the Beer-Lambert law over the finite filter band pass since optical depth changes rapidly with wavelength. The Langley calibration of the radiometers depends critically upon the spectral characterization of each channel and on the wavelength and absolute calibration of the extraterrestrial spectrum used. Results of Langley calibrations for two UV-MFRSRs at Mauna Loa, Hawaii were compared to calibrations using two National Institute of Standards and Technology (NIST) traceable lamps. The objectives of this study were to compare Langley calibration factors with those from standard lamps and to compare field-of-view effects. The two radiometers were run simultaneously: one on a Sun tracker and the other in the conventional shadow-band configuration. Both radiometers were calibrated with two secondary 1000 W lamp, and later, the spectral response functions of the channels were measured. The ratio of Langley to lamp calibration factors for the seven channels from 300 nm to 368 nm using the shadow-band configuration ranged from 0.988 to 1.070. The estimated uncertainty in accuracy of the Langley calibrations ranged from _+3.8% at 300 nm to _+2.1% at 368 nm. For all channels calibrated with Central Ultraviolet Calibration Facility (CUCF) lamps the estimated uncertainty was _+2.5% for all channels.

In the United States, there are several federal agencies interested in the effects of UV radiation, which has resulted in the establishment of UV monitoring programs each with their own instrumentation and sites designed to address their specific needs. In 1993, participating agencies of the U.S. Global Change Research Program organized a UV Panel for coordinating the different agencies' programs in order to ensure that UV data are intercalibrated, have common quality assurance and control procedures, and that the efforts among agencies are not duplicated.In order to achieve these goals, in 1994 the UV Panel recommended formation of the U.S. Central UV Calibration Facility (CUCF), which is operated by the Surface Radiation and Research Branch of the Air Resources Laboratory of National and Oceanic Atmospheric Administration. The CUCF is responsible for characterizing and calibrating UV measuring instruments from several U.S. federal agencies. Part of this effort is to calibrate UVB broadband radiometers from these agencies. The CUCF has three Yankee Environmental Systems (YES UVB-1) and three Solar Light (SL 501A) broadband radiometers as reference standards that are routinely calibrated. For the past three years, clear-sky erythema calibration factors were determined for these standard UVB broadband radiometers by using simultaneously measured erythema-weighted irradiance determined during the annual North American Intercomparison. Comparisons between erythemally weighted irradiance calculated spectra supplied by spectroradiometers typically agreed better than Ϯ2% for solar zenith angles less than 60Њ. The spectroradiometers were participating in an intercomparison event organized by the National Institute of Standards and Technology and the CUCF.In this article, the calibration methodology is described for transferring the calibration from the spectroradiometers to the CUCF's standard broadband radiometers. The CUCF standard broadband radiometers are used to calibrate UVB broadband radiometers from several U.S. UV monitoring networks. Erythemal calibration factors for the CUCF's YES UVB-1 standard broadband radiometer triad are reported for 1994, 1995, and 1996. Erythemal calibration factors for CUCF's SL 501A standard broadband radiometer triad are reported for 1996.