Multiple-injection strategies are characterized by a complex and transient interplay between high-and low-temperature reactions. Tracking low-temperature reaction products such as formaldehyde (CH2O) is particularly important to understand ignition phenomena and the so-called "combustion recession" that is observed in experiments. Experimentally, it is often difficult to discriminate between formaldehyde and other species such as poly-aromatic hydrocarbons, which is why a selective excitation approach is used in this work. Simultaneous high-speed imaging of the chemicallyexcited hydroxyl radical (OH*) is used to improve indication of flame location and second stage ignition. During experiments in a constant-volume vessel, two 0.5-ms injections of n-dodecane, separated by 0.5-ms dwell time, are injected into a 900-K ambient. The global flame development is characterized based on high-speed diagnostics, followed by an investigation into the spatial distribution of formaldehyde at four different times after start-of-injection (aSOI). Results show significant influence of the first injection on characteristics of the second. Ignition delay and lift-off location of the second injection are prominently reduced, while flame penetration is greatly enhanced by the wake of the first injection. Formaldehyde structure is observed during both end-of-injection transients, reaching as far upstream as 6 mm from the nozzle. Even after the second injection, the flame structure still appears to be influenced by the first, with a shorter lift-off length and compressed formaldehyde structure. Based on the selective excitation procedure, it becomes clear that the interpretation of laser-induced fluorescence (LIF) images obtained by 355-nm excitation alone is prone to ambiguity.

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Laser-induced incandescence at high-repetition rates can in principle be used to resolve the temporal evolution of soot processes. The intrusive character of this technique, however, requires due care of historical effects associated with multiple exposures of individual soot particles to laser light. On the other hand, repetitive heating and cooling opens up an independent, acoustic detection channel. We illustrate a photo-acoustic soot volume fraction measurement, and show that the comparison to simultaneously recorded laser-induced incandescence provides qualitative information on soot growth. Experiments are performed on a propane-fueled, co-flow stabilized diffusion flame, and signals are collected at varying heights above the burner deck. Results show a clear correlation between the laser-induced incandescence and photo-acoustic signals; small deviations are interpreted as a qualitative indicator for the particle size.

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