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Groundwater salinization in coastal regions causes severe constraints to water supply and economic losses to society worldwide. In the Azores archipelago, groundwater abstraction in wells drilled in coastal aquifers is very important for water supply, and quality problems have been reported. Therefore, a groundwater chemistry dataset from wells was compiled to study groundwater salinization in these aquifers. Waters are mainly of the Na-Cl type, presenting a slightly acidic to slightly alkaline character, with a pH between 5.63 and 8.50 (median 7.40). Electrical conductivity measurements range from 127 to 9,670 lS/cm (median 862), suggesting highly variable mineralization, with higher values observed on Santa Maria, São Miguel, Pico, Graciosa, and São Jorge islands. The major-ion composition reflects the contribution of seawater to the groundwater compositional evolution, which is essentially explained by seawater intrusion into wells. In many samples, exchange reactions of Na ? ? K ? for Ca 2? ? Mg 2? are associated with salinization. The seawater fraction in groundwater composition reaches a maximum of 22.5%. These results are extremely challenging to water managers in the Azores because failure to comply with national water quality regulations and with European Union groundwater directive requirements often occurs.

Chemical monitoring of water quality on a total of 16 rivers in the Azores archipelago (Portugal), since 2003, made it possible to identify the major pressures and spatial geochemical variations along main course of the rivers. River water pollution is to a large extent associated to point sources, namely domestic wastewater discharges, especially in urban areas, and diffuse sources, associated with pasture land, and explain the high values on BOD(5) and nutrients (P and N). Heavy metals and metalloids, as well as hydrocarbons and pesticides, are generally under the detection limits of the analytical methods. Generally, river water reflects pollution loads according to a simple model, derived from land use in the watershed: in the upper part conditions are pristine, in the intermediate portion of the basin pasture land dominates and near the coast urban discharges are increasingly important. Results stress the role that an approach based on the watershed scale, coupled with land use management measures, are crucial to water management procedures and a successful WFD implementation in small river basin districts like the Azores. The paper also shows the need for full compliance regarding EU directives on urban wastewater and nitrate pollution due to agriculture.

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Little is known about the spatial and temporal variability of the stable isotopic composition of precipitation in the North Atlantic and its relationship to the North Atlantic Oscillation (NAO) and anthropogenic climate change. The islands of the Azores archipelago are uniquely positioned in the middle of the North Atlantic Ocean to address this knowledge gap. A survey of spatial and temporal variability of the stable isotope composition of precipitation in Azores is discussed using newly presented analyses along with Global Network of Isotopes in Precipitation data. The collected precipitation samples yield a new local meteoric water line (δ2H = 7.1 * δ18O + 8.46) for the Azores region and the North Atlantic Ocean. The annual isotopic mean of precipitation shows a small range for the unweighted and precipitation mass‐weighted δ18O‐H2O values. Results show an inverse relation between the monthly δ18O‐H2O and the amount of precipitation, which increases in elevation and into the interior of the island. Higher amounts of precipitation (from convective storm systems) do not correspond to the most depleted values of stable isotopes in precipitation. Precipitation shows an orographic effect with depleted δ18O‐H2O values related to the Rayleigh effect. Monthly δ18O‐H2O values for individual precipitation sampling stations show little relationship to air temperature. Results show a local source of moisture during the summer with the characteristics of the first vapour condensate. The stable isotope composition of precipitation is strongly correlated to the NAO index, and δ18O‐H2O values show a statistically significantly trend towards enrichment since 1962 coincident with the increased air temperature and relative humidity due to climate change. Results are in line with observations of increasing sea surface temperature and relative humidity.